Chloroammelides and their preparation

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

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C07D25146

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043862020

ABSTRACT:
Compounds containing a chloroammelide moiety having the formula ##STR1## wherein R is alkali metal or H, Y is Cl or H, and Y is H when R is H, said compounds being not fully hydrated when R is alkali metal, contain both free and combined chlorine, and are attractive for use in bleaching. Those not fully hydrated can be prepared by removing combined water of hydration from more fully hydrated compounds obtained by chlorinating an aqueous mixture of ammelide and alkali metal ions. The fully hydrated compound wherein R is H is prepared by chlorinating an aqueous mixture of ammelide and about 2-2.2 moles of alkali metal ion per mole of ammelide.

REFERENCES:
patent: 2184886 (1939-12-01), Muskat et al.
patent: 4122268 (1978-10-01), Berkowitz
Potashnik et al., Chemical Abstracts, vol. 70, Entry 47507 (1969).
Verkholetova et al., Tr. Tsent. Nauch-Issled Denzinfek Inst., vol. 19, pp. 128-134 (1970), English Translation.

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