Chlorine dioxide process

Chemistry of inorganic compounds – Halogen or compound thereof – Chlorine dioxide

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423479, 423520, 423551, C01B 1102

Patent

active

044656580

ABSTRACT:
Chlorine dioxide is formed at high efficiency from a solution of acid sodium chlorate at high sulphuric acid normality in excess of 9 normal to which methanol is fed. The reaction medium is at its boiling point under a subatmospheric pressure. The incidence of white-outs is avoided by feeding chloride ions to the reaction medium, while the efficiency of chlorine dioxide production remains high.

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patent: 4325934 (1982-04-01), Swindells et al.
patent: 4409066 (1983-10-01), Reeve et al.

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