Chlorination or chlorosulfonation of polyethylene in mixed solve

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 22, 526 41, C08F 838, C08F 836

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active

041454910

ABSTRACT:
A process for chlorinating or chlorosulfonating polyethylene comprising dissolving polyethylene in a solvent that is a mixture of methylene chloride and trichlorofluoromethane in a weight ratio of 0.3-1.6, reacting the resultant solution with sulfuryl chloride under pressure to maintain reactants, the resulting chlorinated or chlorosulfonated polyethylene and product gases in a single liquid phase, reducing the pressure on or increasing the temperature of the single liquid phase of chlorinated or chlorosulfonated polyethylene and solvent to form two liquid phases, one a polymer-rich phase and the other a solvent-rich phase, and separating the phases.

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patent: 3347835 (1967-10-01), Lorenz
patent: 3542747 (1970-11-01), Ennis
patent: 3960821 (1976-01-01), Vogt

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