Chlorination of ores containing alkali or alkaline earth values

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Alkaline earth metal

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423 72, 423 79, 423 84, 423137, 423494, 423496, 423497, 423499, 75 1R, C01F 530

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active

046524347

ABSTRACT:
The invention pertains to an entrained-downflow chlorination process of fine metalliferous ores particularly containing alkali and/or alkaline earth metals greater than about 0.3% by weight as the oxide. The process includes a quenching step following the chlorination step where the chlorinated products are quenched by liquid cooling fluid spray patterns adapted to prevent solidification of the alkali and/or alkaline earth materials onto the reactor walls. The chlorinator unit of this invention prevents disruption of the chlorination process due to presence of liquids or sticky particles and it contains a quenching spray means disposed below the chlorination zone in the entrained-downflow chlorinator unit, whereby the quenching sprays prevent reactor wall buildup.

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