Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Alkaline earth metal
Patent
1979-07-30
1981-02-03
Vertiz, O. R.
Chemistry of inorganic compounds
Treating mixture to obtain metal containing compound
Alkaline earth metal
13 9R, 423498, C01F 532
Patent
active
042488397
ABSTRACT:
Magnesium oxide is chlorinated in molten impure magnesium chlorine with chlorine gas by adding ferrous chloride to magnesium chloride brine, drying the brine, adding a mixture of calcined petroleum coke and charcoal to the dried brine, melting the product and chlorinating the formed melt. Ferrous chloride is added in amounts sufficient to provide from about 1.0% to 2.2% by weight of iron in the dried product. A highly reactive carbon source is added in amounts of from about 0.8 to 2.3% by weight and a carbon source that is less reactive than the highly reactive carbon source is added in amounts ranging from about 0.8 to 2.3% by weight of dried brine. Iron levels in the magnesium chloride melt may be adjusted upwardly by addition of a mixture of iron oxide and charcoal.
A melt cell characterized by side entry electrodes disposed at angles from 40.degree. to 50.degree., an arched roof configuration, and an improved electrode refractory and ceramic sleeve construction is used to chlorinate the magnesium.
REFERENCES:
patent: 3067006 (1962-12-01), Ebert et al.
patent: 3512928 (1970-05-01), Lyons et al.
patent: 3953574 (1976-04-01), Toomey
Darlington R. Keith
Davis Brian R.
Neelameggham Ramaswami
Toomey Robert D.
Langel Wayne A.
NL Industries Inc.
Vertiz O. R.
White Gerald K.
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