Chlorination leaching with sulfur extraction for recovery of zin

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group iib metal

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423568, 75104, 75120, C25C 116, C22B 1922, C01G 904, C01B 1706

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043460623

ABSTRACT:
A process is disclosed for recovering zinc from a material containing zinc sulfide. The zinc sulfide-containing material is chlorinated in an aqueous medium to form zinc chloride and elemental sulfur. A water-immiscible solvent (preferably inert) for the sulfur is added to the aqueous chlorinating solution during the chlorination process. The aqueous solution which contains zinc values is separated from the water-immiscible solvent containing sulfur. The zinc values can be recovered from the aqueous layer.

REFERENCES:
patent: 1838857 (1931-12-01), Mitchell
patent: 3927170 (1975-12-01), Dixon
patent: 3998628 (1976-12-01), Gandon
patent: 4206023 (1980-06-01), Au
Haver, "Recovering Elemental Sulfur from Non-Ferrous Minerals, U.S. Bureau of Mines", R. I. 7474, (1971), pp. 1-18.

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