Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...
Reexamination Certificate
1998-12-03
2001-10-23
Mulcahy, Peter D. (Department: 1713)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
At least one aryl ring which is part of a fused or bridged...
C524S567000
Reexamination Certificate
active
06306950
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a chlorinated vinyl chloride resin composition. In particular, the present invention relates to a chlorinated vinyl chloride resin composition containing titanium dioxide which improves the thermal stability of the composition.
2. Prior Art
Shaped articles of chlorinated vinyl chloride resin compositions have characteristics such as high heat resistance and are used at relatively high temperatures at which conventional vinyl chloride resin compositions cannot be used due to thermal deformation. For example, the shaped articles of chlorinated vinyl chloride resin compositions are used in the form of a pipe for hot water by making use of the high thermal deformation temperature which is 20 to 40° C. higher than that of the shaped articles of vinyl chloride resin compositions.
In the case of shaping, chlorinated vinyl chloride resins have a drawback that they have inferior thermal stability to vinyl chloride resin compositions, and thus they tend to be burnt in a shaping process. For example, a chlorinated vinyl chloride resin is colored when it is extrusion molded to produce a pipe for hot water, or in some cases, it is burnt during extrusion molding. Thus, such a produced pipe may not be commercially sold.
SUMMARY OF THE INVENTION
One object of the present invention is to provide a chlorinated vinyl chloride resin composition having good thermal stability, in particular, for the production of pipes.
Accordingly, the present invention provides a chlorinated vinyl chloride resin composition comprising a chlorinated vinyl chloride resin which has a polymerization degree of from 600 to 1500 prior to chlorination and a chlorination degree of from 62 to 70 wt. %, an impact modifier, a stabilizer, a lubricant and titanium dioxide, wherein the content of zinc in titanium dioxide is 0.1% or less.
DETAILED DESCRIPTION OF THE INVENTION
A vinyl chloride resin (prior to post-chlorination), which is a raw material of a chlorinated vinyl chloride resin contained in the composition of the present invention, has a polymerization degree of from 600 to 1500, preferably from 600 to 1300, more preferably from 600 to 1200. The chlorination degree of the chlorinated vinyl chloride resin is from 62 to 70 wt. %, preferably from 63 to 70 wt. %, more preferably from 65 to 70 wt. %.
When the polymerization degree of a vinyl chloride resin as the raw material of a chlorinated vinyl chloride resin is less than 600, sufficient mechanical strength cannot be attained. When this polymerization degree exceeds 1500, the processing of the resin composition is not easy.
When the chlorination degree of a chlorinated vinyl chloride resin is less than 62 wt. %, a resin composition does not have sufficient heat resistance. When the chlorination degree exceeds 70 wt. %, the resin has a high melt viscosity, and thus the processing of a resin composition undesirably encounters technical problems.
Herein, “vinyl chloride resins” include vinyl chloride homopolymers, and also copolymers of vinyl chloride with other copolymerizable monomer (e.g. ethylene, propylene, vinyl acetate, allyl chloride, allyl glycidyl ether, acrylate esters, vinyl ethers, etc.).
The composition of the present invention is characterized in the use of titanium dioxide containing 0.1% or less of zinc. The use of such titanium dioxide containing the small amount of zinc significantly improves the thermal stability of a resin composition.
Titanium dioxide having such a low zinc content can be produced by a chlorine method, while titanium dioxide is usually produced by a sulfuric acid method. Titanium dioxide having such a low zinc content is commercially available.
The amount of titanium dioxide is preferably at least 1 wt. parts, more preferably at least 2 wt. parts, per 100 wt. parts of the chlorinated vinyl chloride resin. When the amount of titanium dioxide is less than 1 wt. parts, the inherent whitening effect of zinc dioxide deteriorates, and obtained shaped articles, in particular, pipes have decreased impact strength.
The upper limit of the amount of titanium dioxide is not critical. Practically, the amount of titanium dioxide does not exceed 10 wt. parts per 100 wt. parts of the chlorinated vinyl chloride resin.
It is preferable for the chlorinated vinyl chloride resin composition of the present invention to contain an impact modifier, a stabilizer, a lubricant, etc. in addition to titanium dioxide so that the composition has well balanced impact resistance and heat resistance by taking processability into account.
An impact modifier may be any of conventionally used impact modifiers for chlorinated vinyl chloride resins, for example, those comprising MBS, ABS, MABS, chlorinated polyethylene (CPE), acrylic rubber, etc.
In particular, MBS or the combination of MBS and chlorinated polyethylene is preferably used as an impact modifier to balance the impact resistance and heat resistance. For the same reason, the amount of an impact modifier or impact modifiers is preferably between 4 and 15 wt. parts, more preferably between 4 and 12 wt. parts, per 100 wt. parts of a chlorinated vinyl chloride resin.
Stabilizers may be any conventional stabilizers for chlorinated vinyl chloride resins such as tin-base stabilizers, lead-base stabilizers, etc. Among them, tin-base stabilizers are preferable. Titanium dioxide containing such a small amount of zinc can most effectively display its effect to improve the thermal stability, when a tin-base stabilizer is used as a stabilizer.
Preferable examples of tin-base stabilizers are alkyltin compounds (e.g. methyltin, butyltin, octyltin, mixed metal alkyltin, etc.). Other examples of tin-base stabilizers are mercaptomethyltin, mercaptooctyltin, mercaptobutyltin, dialkyltinbis (alkylmercaptocarboxylate salt), octyltinmaleate, butyltin maleate, octyltin laurate, butyltin laurate, butyltin lauratemaleate, octyltin carboxylate, butyltin carboxylate, etc.
The amount of a stabilizer is preferably from 1.5 to 5 wt. parts, more preferably from 1.5 to 4 wt. parts, per 100 wt. parts of a chlorinated vinyl chloride resin. When the amount of a stabilizer is less than 1.5 wt. parts, the thermal stability of a chlorinated vinyl chloride resin composition deteriorates. When the amount of the stabilizer exceeds 5 wt. parts, the effect to improve the thermal stability reaches the limit, and thus the thermal stability is not improved in a degree comparable to the added amount of the stabilizer.
Examples of lubricants are polyglycerol of di- or trioleate, polyethylene, oxidized polyethylene, high molecular weight paraffin waxes, etc. Among them, polyethylene waxes are preferable.
The amount of a lubricant is preferably from 1.5 to 4 wt. parts, more preferably from 1.5 to 3 wt. parts, per 100 wt. parts of a chlorinated vinyl chloride resin. When the amount of a lubricant is less than 1.5 wt. parts, the composition has a high melt viscosity, and thus its extrusion precessability deteriorates. When the amount of a lubricant exceeds 4 wt. parts, the lubricity of the resin against metals becomes too high, and thus the composition may pulsate when it is discharged in the extrusion processing process.
The chlorinated vinyl chloride resin composition of the present invention may optionally contain other additives, which are compounded in conventional chlorinated vinyl chloride resin compositions, in addition to the above additives. Examples of the other additives are acrylic processing aids, colorants, and the like.
The chlorinated vinyl chloride resin composition of the present invention may be prepared by any conventional methods. For example, all the additives are added to the chlorinated vinyl chloride resin at a time and kneaded. Alternatively, the additives are added to the chlorinated vinyl chloride resin one after another and kneaded.
The kneading may be carried out with any conventional kneading machines.
REFERENCES:
patent: 5274043 (1993-12-01), Greenlee et al.
patent: 2176650 (1996-11-01), None
patent: 510 310 (1992-10-01), None
patent: 603 7
Isshiki Minoru
Okuhara Toshio
Suzuki Takeyuki
Foley & Lardner
Kaneka Corporation
Mulcahy Peter D.
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