Chlorides of lead, zinz, copper, silver and gold

Chemistry of inorganic compounds – Halogen or compound thereof – Binary compound containing metal

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423493, 423494, 423DIG12, 423 46, 423 89, 423 99, 75111, 75112, C01G 2116, C01G 904, C01G 304, C01G 500, C01G 700

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042095018

ABSTRACT:
A process for forming a metal chloride of a metal or its compound comprising forming a liquid fused salt bath mixture of at least two metal chlorides with one of the chlorides being selected from the group consisting of ferric chloride, ferrous chloride, cupric chloride and cuprous chloride, and introducing the metal or compound into the liquid fused salt bath in the presence of a chlorine source to form the metal chloride and elemental sulfur, and recovering the formed chloride from the liquid fused salt bath mixture. Chlorine gas or sulfur chloride may be introduced into the bath as an additional source of chlorine for reaction with the metal and for the generation of a portion of the ferrous chloride or cuprous chloride into ferric chloride or cupric chloride.

REFERENCES:
patent: 1388086 (1921-08-01), Ashcroft
patent: 3679359 (1972-07-01), Haberland et al.
patent: 3894927 (1975-07-01), Kane et al.
patent: 3988417 (1976-10-01), Polinsky
Beck et al., "APC Printed Publication", S.N. 292742, Jul. 13, 1943.
Beck et al., "APC Printed Publication", S.N. 393258, Jul. 13, 1943.
Delarue, "Chimie Analytique", vol. 44, Mar. 1962, pp. 91-101 (Translation pp. 1-29.

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