Chloride assisted hydrometallurgical extraction of metal

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group ib metal

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23293S, 75743, 75744, 205582, 205583, 205584, 205604, 205606, 205607, 205570, 209165, 423 27, 423 41, 423 99, 423109, 4235782, B01D 1102, C22B 1100, C22B 1500, C22B 1900

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058690123

ABSTRACT:
A process for the extraction of zinc from a sulphide ore or concentrate containing copper and zinc includes subjecting the concentrate to pressure oxidation in the presence of oxygen and an acidic halide solution to obtain a resulting pressure oxidation slurry and subjecting the slurry to a liquid/solid separation step to produce a liquor containing copper and zinc in solution. The liquor containing the copper and zinc is subjected to a first solvent extraction with a copper extractant to remove copper from the solution and to produce a copper depleted raffinate. The copper depleted raffinate is subjected to a second solid extraction with a zinc extractant to produce a zinc depleted raffinate and the zinc depleted raffinate is recycled to the pressure oxidation step.

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Flett, D.S., "Solvent Extraction in Copper Hydrometallurgy: A Review", Transactions of the Institution of Mining & Metallurgy; Mar., 1974, pp. C30-C37.

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