Chiral synthesis units from prochiral glycerol

Details Chiral synthesis units from prochiral glycerol Chiral synthesis units from prochiral glycerol

1987-07-20

1990-05-01

Killos, Paul J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

2604106, 560187, 560189, 560 61, 560155, 560173, C07C 6976

Patent

active

049220012

ABSTRACT:
Differentiation of the two enantiotopic groups in prochiral glycerol derivatives gives chiral molecules directly, which in turn are easily converted either into the S-series or into the R-series by selective manipulation of the functional groups.

REFERENCES:
Weber, A. et al., CA 102(17):146207u, 1985.
Baran, J., CA 87(5):39430m, 1977.
CA(102)(17):148998b, 1984.
Mueller, H., CA 106(17) 137922d.
Mueller et al., Tetrahedron, vol. 42, No. 5, 1986, pp. 1533-1538.
Baran et al., Journal of Organic Chemistry, vol. 42, No. 13, 1977, pp. 2260-2264.
Weber (Eur. J. Biochem., 146, 1985, pp. 323-329).

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