Chiral compounds of the beta-binaphthyl type, their preparation

Organic compounds -- part of the class 532-570 series – Organic compounds – Boron containing

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568 1, 568 6, C07F 502

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050535463

ABSTRACT:
New chiral compounds of the formula ##STR1## a process for their preparation and their use for the preparation of optically active compounds.

REFERENCES:
patent: 3230262 (1966-01-01), Koster
patent: 4284581 (1981-08-01), Noyori
patent: 4644075 (1987-02-01), Masamune
patent: 4713380 (1987-12-01), Brown
patent: 4772752 (1988-09-01), Brown
Chemical Abstracts vol. 108, Jan. 1988, Asymmetric reduction of prochiral arylketones with chiral 2,2'-dihydroxy-1,1'-binaphthylborane complexes p. 533.
Journal of Organometallic Chemistry vol. 344, 1988, Erste asymmetrische Synthese beta-binaphthylgestutzter Silane, Stannane und Borane pp. 277-283 U. M. Gross et al.
Tetrahedron Letters vol. 29, 1988, Chirality transfer from silicon to carbon: use of optically pure cyclic silanes with a binaphthalene chiral unit pp. 6199-6202.

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