Chiral azetidinone derivatives, and their use as dopes in liquid

Compositions – Liquid crystal compositions – Containing nonsteryl liquid crystalline compound of...

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540357, 540361, 540363, C09K 1934, C07D20508

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053343280

ABSTRACT:
Azetidinones of the formula I ##STR1## in which, for example, R.sup.1 is an alkyl or alkenyl radical, R.sup.2 and R.sup.3 are hydrogen or an alkyl or alkenyl radical, Z is hydrogen or (pseudo)halogen, A.sup.1, A.sup.2 and A.sup.3 are a ring system, and M is a spacer group, can be added to liquid-crystal mixtures. Even when admixed in small amounts, they cause considerable twist in the cholesteric and smectic C* phase, which can compensate the pitch of another dope or produce a short S.sub.C * pitch.

REFERENCES:
Japanese Journal of Applied Physics, Bd. 27, Nr. 12, 1988, Tokyo, pp. L2241-L2244, H. R. Duball, "Three classes of new chiral dopants: Synthesis and Physical Qualifications as Dopants for Practical FLC-Mixtures".

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