Chevrel-phase syntheses and electrochemical cells

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

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429225, 2521821, H01M 458

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active

050413473

ABSTRACT:
Methods of making Chevrel-phase materials suitable for use as battery cathodes by heating a precursor composition comprising one or more heat labile compounds of one or more non-molybdenum metals capale of forming a Chevrel-phase material, forming a reaction mixture with molybdenum and a chalcogen or compounds thereof, and further heating said reaction mixture. Chevrel-phase materials having two non-molybdenum metals in which one serves as a filler metal resistant to intercalation. Electrochemical cells incorporating the Chevrel-phase materials disclosed.

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Schneider et al., Chemical Abstracts, vol. 105, No. 46382, 8/86.
Mulhern et al., "Rechargeable Nonaqueous lithium/Mo.sub.6 S.sub.8 Battery", Canadian Journal of Physics, v. 62, pp. 527-531, 1984.
McKinnon et al., "Structure and Chemistry of LixMo.sub.6 S.sub.8 " Physical Review B., v. 31, No. 5, pp. 3084-3087. 1 Mar. 1985.

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