Chemical synthesis of conducting polypyrrole using uniform oxida

Coating processes – Electrical product produced – Cellulosic or fibrous base

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427301, 427302, 4274071, 4274072, 4274073, 427412, 4274125, 4274198, 526258, 528423, 252500, 252518, 252519, B05D 512, H01B 106

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048471151

ABSTRACT:
A method for producing oxidant/dopant reagent solutions which comprises reacting a basic ferric carboxylate, preferably basic ferric acetate, with an alkyl or aryl sulfonic acid, e.g., benzenesulfonic acid, to produce the corresponding ferric sulfonate in solution. Oxidant/dopant solutions can also be prepared containing cupric or ceric sulfonates. The oxidant/dopant solution is employed in situ for reaction with a pyrrole to produce electrically conductive polypyrrole. A porous substrate, such as fiberglass cloth, can be dipped in the oxidant/dopant solution, dried and then treated with a pyrrole to produce an electrically conductive polypyrrole deposit in the interstices of the substrate.

REFERENCES:
patent: 4567250 (1986-01-01), Narmunn et al.
patent: 4585695 (1986-04-01), Igasawara et al.
patent: 4697001 (1987-09-01), Walker et al.

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