Chemical synthesis of a chiral 1,4-oxazin-2-one

Organic compounds -- part of the class 532-570 series – Organic compounds – Chalcogen in the nitrogen containing substituent

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Details

544106, 544107, 544173, C07D26530, C07D26532

Patent

active

061303313

ABSTRACT:
The present invention relates to a process for the preparation of substantially pure N-((S)-(-)-.alpha.-methylbenzyl)-3-(S)-(4-fluorophenyl)-1,4-oxazin-2-one hydrochloride, which comprises selectively crystallising the (S,S)-diastereomer as the hydrochloride salt from a mixture of the (S,R)- and (S,S)-diastereomers in an organic solvent, and collecting the resultant crystalline product.

REFERENCES:
patent: 6046325 (2000-04-01), Ashwood et al.

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