Chemical sensor with an indicator dye

Chemical apparatus and process disinfecting – deodorizing – preser – Analyzer – structured indicator – or manipulative laboratory... – Means for analyzing liquid or solid sample

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C422S051000, C422S051000, C422S082050, C422S083000, C436S169000, C356S073100, C356S128000, C385S143000, C385S145000

Reexamination Certificate

active

07842243

ABSTRACT:
A chemical sensor based on an indicator dye wherein a light transmissive element containing the indicator dye is made of a hygroscopic polymer. The polymer may be, for example, a polyimide or PMMA or other polymer. In an alternative embodiment the light transmissive element is doped with metal nanocolloidal particles. One embodiment may include a reference photodiode and differential amplifier to compensate for the fluctuations of the intensity of the light source. The light source may be pulse modulated. The sensor may include calibration means comprising a reference sample of the chemical to be detected and a precision delivery means. A method of fabricating the polymer and metal nanocolloid is disclosed wherein the nanocolloid is produced by generating a pulsed laser plasma in a suspension of metal particles and an organic solvent and adding the resulting solvent colloid to a solution containing the polymer.

REFERENCES:
patent: 4513087 (1985-04-01), Giuliani et al.
patent: 4761710 (1988-08-01), Chen
patent: 5640234 (1997-06-01), Roth et al.
patent: 5774603 (1998-06-01), Moore et al.
patent: 6778316 (2004-08-01), Halas et al.
Sarkisov et al, “Planar optical waveguide sensor of ammonia”, Dec. 7, 2004, Advanced Environmental, Chemical, and Biological Sensing Technologies II, vol. 5586, pp. 33-44.
Dakin, J., and Culshaw, B., Optical fiber sensors. vol. 4: Applications, Analysis, and Future Trends, Artech House, Boston, 1997, pp. 53-80 and pp. 95-97.
Boisde, G., and Harmer, A., Chemical and biochemical sensing with optical fibers and waveguides, Artech House, Boston, 1996, pp. 65-84.
Klein, R., and Voges, E.I., “Integrated optics ammonia sensor,” Advances in fluorescence sensing technology, edited by J.R. Lakowicz and R.B. Thompson, Proceedings of SPIE, vol. 1885, SPIE, Bellingham, WA, 1993, 81-92.
Caglar, P., and Narayanaswamy, R., “Ammonia-sensitive fibre optic probe utilizing an immobilized spectrophotometric indicator,” Analyst, vol. 112, 1987, pp. 1285-1288.
Hartman; N.F., Walsh, J.L., Campbell, D.P., and Akki, U., “Integrated optic gaseous NH3 sensor for agricultural applications,” Optics in Agriculture, Forestry, and Biological Processing, edited by G.E. Meyer and J. A. DeShazer, Proceedings of SPIE, vol. 2345, SPIE, Bellingham, WA, 1995, pp. 314-323.
Bowman, E.M. and Burgess L.W., “Evaluation of polymeric thin film waveguides as chemical sensors,” Chemical, Biochemical, and Environmental Fiber Sensors II, Proceedings of SPIE, vol. 1368, SPIE, Bellingham, WA, 1990, 239-250.
Lieberman, R.A., Ferrell, D.J., Schmidlin, E.M., Syracuse, S.J., Khalil, A.N., Mendoza, E.A., “Reversible sensor for carbon monoxide based on dye-doped porous fiber optic fiber,” Proceedings of SPIE, vol. 1796, SPIE, Bellingham, WA, 1992, 324-331.
Zh. Qi, A. Yimit, K. Itoh, M. Murabayashi, N. Matsuda, A. Takatsu, and K. Kato, Composite optical waveguide composed of a tapered film of bromothymol blue evaporated onto a potassium ion-exchanged waveguide and its application as a guided wave absorption-based ammonia gas sensor, Opt. Lett., vol. 26, No. 9, 2001, 629-631.
Hummel, Rolf E. and Wismann, P, “Handbook of Optical Properties, vol. II, Optics of Small Particles, Interfaces, and Surfaces” CRC Press, Inc. 1997 pp. 191-197.
Pranjoto, Hartono and Denton, Denice “Gravimetric measurements of steady state moisture uptake in spin coated polyimide films” Journal of Applied Polymer Science vol. 42, Issue 1, abstract for pp. 75-83, Mar. 10, 2003.
Amoco Chemical, “Ultradel 9020D Coatings” Bulletin UL-P13.
Amoco Chemical, “Ultradel 9020D Process Guidelines” Bulletin UL-PG7.
Cahill, PA, et al. “Polyimide Based Electrooptic Materials” Nonlinear Optical Properties of Organic Materials VI, Jul. 13, 1993, Society of Photo-Optical Instrumentation Engineers, pp. 48-55.
Sarkisov, Sergey et al. “Single-arm double-mode double-order planar waveguide interferometric sensor,” Applied Optics, Jan. 20, 2001, vol. 40, No. 3, Optical Society of America, pp. 349-359.
Yimit, Abliz et al. “Detection of Ammonia in the ppt range based on a composite optical waveguide pH sensor,” Sensors and Actuators B 88 (2003) pp. 239-345, 2002 Elsevier Science B. V.
Giuliani, J.F. et al., “Reversible optical waveguide sensor for ammonia vapors,” Optics Letters, vol. 8, No. 1, Jan. 1983, Optical Society of America, pp. 54-56.
Siegel, R. W., Hu, E., and Roco, M.C., editors “Nanostructure Science and Technology: R&D Status and Trends in Nanoparticles, Nanostructured Materials, and Nanodevices.” National Science and Technology Council. Kluwer Academic Publishers, 1999, Chapters 2, 7. PDF document.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Chemical sensor with an indicator dye does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Chemical sensor with an indicator dye, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Chemical sensor with an indicator dye will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4240646

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.