Chemical process

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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C07C 5923

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active

049594966

ABSTRACT:
There is disclosed herein improved processes for the preparation of ether carboxylates by reacting in an alkaline reaction medium the salts of maleic acid and a carboxylic or polycarboxylic acid having a reactive hydroxyl group on a non-carbonyl carbon atom in the presence of a calcium ion catalyst wherein unreacted acid salts are recovered from the reaction medium by lowering the pH of the reaction medium to a range of from about 4 to about 6. The precipitated salts are recycled to the synthesis reaction to prepare additional amounts of product.

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patent: 3914297 (1975-10-01), Lamberti et al.
patent: 4663071 (1987-05-01), Bush et al.
patent: 4689167 (1987-08-01), Collins et al.
Chemical Abstracts, vol. 60, 2295G, 1964.
Chemical Abstracts, vol. 64, 4224G, 1966.

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