Chemical overcharge protection of lithium and lithium-ion second

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

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429192, 296231, H01M 1040

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active

058585737

ABSTRACT:
This invention features the use of redox reagents, dissolved in non-aqueous electrolytes, to provide overcharge protection for cells having lithium metal or lithium-ion negative electrodes (anodes). In particular, the invention features the use of a class of compounds consisting of thianthrene and its derivatives as redox shuttle reagents to provide overcharge protection. Specific examples of this invention are thianthrene and 2,7-diacetyl thianthrene. One example of a rechargeable battery in which 2,7-diacetyl thianthrene is used has carbon negative electrode (anode) and spinet LiMn.sub.2 O.sub.4 positive electrode (cathode).

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Prema, S. and Srinivasan, M., "Preparation and Properties of Polyamides Containing Thianthrene Units," Eur. Polym. J., vol. 23, No. 11, pp. 897-903, 1987. (Month unknown).

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