Chemical heat pump and chemical energy storage system

Refrigeration – Refrigeration producer – Sorbent type

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Details

622383, 622351, 126400, 237 2B, F25B 1700

Patent

active

045327785

ABSTRACT:
A chemical heat pump and storage system employs sulfuric acid and water. In one form, the system includes a generator and condenser, an evaporator and absorber, aqueous acid solution storage and water storage. During a charging cycle, heat is provided to the generator from a heat source to concentrate the acid solution while heat is removed from the condenser to condense the water vapor produced in the generator. Water is then stored in the storage tank. Heat is thus stored in the form of chemical energy in the concentrated acid. The heat removed from the water vapor can be supplied to a heat load of proper temperature or can be rejected. During a discharge cycle, water in the evaporator is supplied with heat to generate water vapor, which is transmitted to the absorber where it is condensed and absorbed into the concentrated acid. Both heats of dilution and condensation of water are removed from the thus diluted acid. During the discharge cycle the system functions as a heat pump in which heat is added to the system at a low temperature and removed from the system at a high temperature. The diluted acid is stored in an acid storage tank or is routed directly to the generator for reconcentration. The generator, condenser, evaporator, and absorber all are operated under pressure conditions specified by the desired temperature levels for a given application. The storage tanks, however, can be maintained at or near ambient pressure conditions. In another form, the heat pump system is employed to provide usable heat from waste process heat by upgrading the temperature of the waste heat.

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Clark et al., "Development Status and Utility of the Sulfuric Acid Chemical Heat Pump/Chemical Storage System", Energy Conversion Engineering Conference, Aug. 18-22, 1980.
Clark et al., "Sulfuric Acid-Water Heat Pump/Energy Storage System Demonstration, ASME Energy Storage Session, Dec. 1978.
Huxtable et al., "Thermal Energy Storage by Sulfuric Acid-Water System", International Solar Energy Society Meeting, vol. 8, pp. 178-191, 1976.
Smith, Storage in Solar Energy Systems, International Solar Energy Society, UK Section, Feb. 1978.
Hiller et al., Chemical Heat Pump/Energy Storage System Demonstration Using Sulfuric Acid and Water, Proceedings of Solar Energy Storage Options Conference, San Antonio, Texas, Mar. 19-20, 1979, pp. 441-454.
Sundahl, R. O. et al., Temperature Boosting & Energy Storage by Heat of Dilution, Sandia Laboratories, Livermore, Report SLL-74-0224, May 1974.

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