Cleaning and liquid contact with solids – Processes – For metallic – siliceous – or calcareous basework – including...
Reexamination Certificate
2000-10-19
2001-05-15
Carrillo, Sharidan (Department: 1746)
Cleaning and liquid contact with solids
Processes
For metallic, siliceous, or calcareous basework, including...
C134S002000, C134S019000, C134S030000, C134S041000, C510S201000, C510S202000, C510S241000, C510S242000, C510S245000, C510S254000, C510S434000, C510S477000
Reexamination Certificate
active
06231678
ABSTRACT:
TECHNICAL FIELD
The invention relates generally to a composition of matter, and a method (and system) for using it, for removing coatings of various kinds on aluminum scrap and other substrates prior to or during the recycling process. The composition of matter is aqueous and contains at least one short chain organic acid; the method includes applying the composition to the substrate with the application of heat and agitation.
BACKGROUND OF THE INVENTION
For thirty years or more, aluminum scrap such as shredded mixed “used beverage containers” (UBCs) has been recycled as a cost effective way to manufacture aluminum metal, as contrasted with the refining of aluminum ore. U.S. patents representative of basic recycling technology include, for example, U.S. Pat. Nos. 3,997,336, No. 4,128,415, and No. 4,983,216, all to van Linden et al. When shredded mixed UBCs were historically recycled without removal of the coatings thereon, the aluminum recovery during recycling was very poor. An early process for coating removal, which is still in use at this writing, is a thermal delacquering process in which shredded mixed UBCs are subjected to heating to a temperature slightly under the melting point of the aluminum. The high temperatures literally incinerate the coatings so as to remove them, and delacquered shredded mixed UBCs of this type can be recycled with very high recovery of aluminum metal.
Thermal delacquering has at least two major disadvantages, however, as a method for removing coatings from aluminum scrap prior to recycling. First, the gaseous effluent created from what amounts to combustion of the coatings requires further environmental remediation. Also, thermal delacquering of aluminum scrap itself creates a loss of some of the otherwise recyclable metal.
Other prior art efforts to remove coatings have included the use of chemical delacquering compositions. For example, Fujisawa et al., “Swell-Peeling Method for Paints on Aluminum Cans,” Metallurgical Review of Mining and Materials Processing Institute, vol. 16, no. 1, 1999, discuss the use of methylene chloride alone or in combination with formic acid and/or acetic acid as a composition to promote the swelling, peeling and removal of paints coated on aluminum cans. The combination of methylene chloride, formic acid and halogenated acetic acid is reported to effect better coating removal than can be achieved with methylene chloride alone or methylene chloride in combination with formic acid. Unfortunately, the compositions of Fujisawa et al. and others are plagued by environmental unsuitability. Methylene chloride and formic acid are each both volatile and hazardous, which make handling these materials cumbersome and expensive. Prior art attempts to use methyl ethyl ketone or sulfuric acid created similar environmental obstacles and, ironically, many strong acids such as sulfuric acid proved surprisingly ineffective as delacquering agents.
Certain prior art U.S. patents have addressed the chemical removal of coatings from aluminum or metal scrap. U.S. Pat. No. 5,817,163 to Wood describes a two step process which applies superheated steam @ 1000° F. to the coated scrap prior to traditional thermal delacquering. The superheated steam is disclosed as producing a carbon-containing volatile from the carbon-containing coatings, which carbon-containing volatile can be removed from the spent steam to prevent its fugitive emission. U.S. Pat. Nos. 5,423,922 and No. 5,494,603 to Kirk disclose a delacquering composition containing primarily polyalkylene glycol polymer and an aqueous solution of a smaller amount of a dicarboxylic acid such as oxalic, malonic, succinic, glutaric, or adipic acid (alone or in combination). The disadvantage with superheated steam is its higher energy requirement and inconsistent effectiveness. Polyalkylene glycol polymers are difficult to handle, inasmuch as they require consideration of human exposure issues and waste disposal issues, and would also inevitably partially remain on the metal thus treated. During subsequent heating and melting, any remaining polyalkylene glycol polymer would then likely decompose and release undesirable emission products, and would likely also contribute to unwanted metal oxidation at the same time.
In view of the disadvantages by which the prior art is plagued, the present invention seeks to provide delacquering of coatings from coated aluminum and other scrap or substrates by means of compositions and methods which give improved metal recovery yields and which are environmentally acceptable or optimal.
SUMMARY OF THE INVENTION
In order to meet these goals, the present invention is a chemical delacquering composition and process in which an aqueous solution containing at least one short-chain organic acid, preferably a mixture of two short-chain organic acids, and optional components such as surfactants, are contacted onto coated aluminum (or other substrates) with application of heat and agitation. The invention embraces the use of one or more organic acids (carboxylic acids) having a total of 2-12 carbons, preferably 3-8 carbons. Concentration of organic acid by weight ranges from about 0.5-8% per at least one organic acid, or preferably 2-4% for each organic acid component assuming two organic acid components are present. In the preferred embodiment of the invention, about 2-4% each of citric and lactic acids are present in the delacquering composition. Processing temperatures range from 160-212° F., preferably 180-212° F., and most preferably 185-212° F. (higher temperatures maybe used in pressurized reactors, although pressurized reactors are not generally necessary). The shredded mixed UBCs or other substrates to be chemically delacquered are contacted with the composition and—before, during and/or after heating—are stirred, drummed or otherwise agitated to facilitate coating removal. Processing times range from about 12-120 minutes (larger batch sizes required shorter times) and commercial processing times will often fall within the preferred range of 30 minutes to 1 hour. Coatings treated with the present composition and method do not generally dissolve completely but usually delaminate into flecks or leaves of coating material, which may in turn be filtered from the treating composition.
REFERENCES:
patent: 3997336 (1976-12-01), van Linden et al.
patent: 4128415 (1978-12-01), van Linden et al.
patent: 4244792 (1981-01-01), Baldwin
patent: 4481061 (1984-11-01), Ross
patent: 4980076 (1990-12-01), Tamaka et al.
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patent: 5232619 (1993-08-01), Sue
patent: 5290362 (1994-03-01), Sue
patent: 5310496 (1994-05-01), Taylor
patent: 5391234 (1995-02-01), Murphy
patent: 5423922 (1995-06-01), Kirk
patent: 5494603 (1996-02-01), Kirk
patent: 5669980 (1997-09-01), McNeil et al.
patent: 5707697 (1998-01-01), Spain et al.
patent: 5817163 (1998-10-01), Wood
patent: 5977041 (1999-11-01), Honda
patent: 6093657 (2000-07-01), Ohkubo et al.
Fujisawa et al., “Swell-Peeling Method For Paints On Aluminum Cans,”Metallurgical Review of MMIJ, vol. 16, No. 1, pp. 15-22 (1999).
Arruda Doris
Tomaswick Kathleen M.
Alcoa Inc.
Carrillo Sharidan
Johnson Barbara E.
Levine Edward L.
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