Chemistry: electrical and wave energy – Apparatus – Electrolytic
Patent
1983-04-07
1984-10-09
Niebling, John F.
Chemistry: electrical and wave energy
Apparatus
Electrolytic
429111, 427 82, C25B 1100
Patent
active
044760035
ABSTRACT:
According to the present invention, an improved method of coating electrodes with conductive polymer films and/or preselected catalysts is provided. The charge-conductive polymer is covalently or coordinatively attached to the electrode surface to strengthen the adhesion characteristics of the polymer to the electrode surface or to improve charge-conductive properties between the conductive polymer and the electrode surface. Covalent or coordinative attachment is achieved by a number of alternative methods including covalently or coordinatively attaching the desired monomer to the electrode by means of a suitable coupling reagent and, thereafter, electrochemically polymerizing the monomer in situ.
REFERENCES:
patent: 4379740 (1983-04-01), Nazzal
Yoneyama et al., J. Electroanal. Chem. 108 (1980), 87-95.
Simon et al., J. Am. Chem. Soc. 1982, 104, 2031-2034.
Bookbinder et al., Proc. Natl. Acad. Sci., vol. 77, No. 11, pp. 6280-6284, Nov. 1980.
Fox et al., J. Am. Chem. Soc., 102:12, 4036-4039, Jun. 1980.
Noufi et al., J. Am. Chem. Soc. 1981, 103, 1849-1850.
Frank Arthur J.
Honda Kenji
Esposito Michael F.
Niebling John F.
Richardson Kenneth L.
The United States of America as represented by the United States
Weinberger James W.
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