Certain substituted 3-amino-2-benzoylcyclohex-2-enones

Details Certain substituted 3-amino-2-benzoylcyclohex-2-enones Certain substituted 3-amino-2-benzoylcyclohex-2-enones

1986-06-09

1988-10-04

Hollrah, Glennon H.

Chemistry: fertilizers

Processes and products

Forms or conditioning

71 88, 71 98, 71103, 71105, 71123, 564181, 564221, 564305, 564306, 564322, 564440, 564441, 564442, 560 57, 568305, A01N 3302

Patent

active

047754117

ABSTRACT:
A compound of the formula ##STR1## wherein R is halogen, C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 alkoxy, nitro; cyano; C.sub.1 -C.sub.2 haloalkyl, or R.sup.a SO.sub.n - wherein n is 0 or 2 and R.sup.a is C.sub.1 -C.sub.2 alkyl; R.sup.1 is hydrogen or C.sub.1 -C.sub.4 alkyl; R.sup.2 is hydrogen or C.sub.1 -C.sub.4 alkyl; or R.sup.1 and R.sup.2 together are alkylene having 2 to 5 carbon atoms; R.sup.3 is hydrogen or C.sub.1 -C.sub.4 alkyl; R.sup.4 is hydrogen or C.sub.1 -C.sub.4 alkyl; or C.sup.3 and R.sup.4 are oxo; R.sup.5 is hydrogen or C.sub.1 -C.sub.4 alkyl; R.sup.6 is hydrogen or C.sub.1 -C.sub.4 alkyl; and R.sup.7 and R.sup.8 independently are (1) hydrogen; (2) halogen; (3) C.sub.1 -C.sub.4 alkyl; (4) C.sub.1 -C.sub.4 alkoxy; (5) trifluoromethoxy; (6) cyano; (7) nitro; (8) C.sub.1 -C.sub.4 haloalkyl; (9) R.sup.b SO.sub.n - wherein n is the integer 0, 1 or 2; and R.sup.b is (a) C.sub.1 -C.sub.4 alkyl; (b) C.sub.1 -C.sub.4 alkyl substituted with halogen or cyano; (c) phenyl; or (d) benzyl; (10) --NR.sup.c R.sup.d wherein R.sup.c and R.sup.d independently are hydrogen or C.sub.1 -C.sub.4 alkyl; (11) R.sup.e C(O)--wherein R.sup.e is C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkogxy; (12) SO.sub.2 NR.sup.c R.sup.d wherein R.sup.c and R.sup.d are as defined; or (13) --N(R.sup.c)C(O)R.sup.d wherein R.sup.c and R.sup.d are as defined; R.sup.9 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sup.10 is (a) hydrogen; (b) C.sub.1 -C.sub.6 alkyl, (c) C.sub.4 -C.sub.6 cycloalkyl, (d) substituted C.sub.1 -C.sub.6 alkyl, (e) phenyl; (f) substituted phenyl; (g) C.sub.1 -C.sub.6 alkoxy; (h) benzyl; (i) phenethyl; (j) C.sub.1 -C.sub.4 alkyl-C(O)-; (k) C.sub.1 -C.sub.4 alkyoxy-C(O)-; (1) C.sub.2 -C.sub.6 alkenyl; or (m) C.sub.2 -C.sub.6 alkynyl; and R.sup.9 and R.sup.10 together form a heterocyclic ring with the nitrogen to which they are attached containing 0, 1 or 2 additional hetero atoms (nitrogen, sulfur or oxygen).

REFERENCES:
Tamura, Y. et al, "Photochemical Dealkylation, etc" Chem. Pharm. Bull. pp. 1692-1696 (1982).

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