Certain .beta.-diketones and the use thereof as metal extractant

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260592, 260465D, 260465G, 423 34, C07C 4976

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active

040655024

ABSTRACT:
New .beta.-diketones of the structure ##STR1## where R is phenyl or alkyl substituted phenyl, R' is alkyl, alkyl substituted phenyl or chloro substituted phenyl and R" is H or --CN with the provisos that; (1) when R is phenyl, R' is a branched chain alkyl group of at least seven carbon atoms and (2) when R is alkyl substituted phenyl, the number of carbon atoms in the alkyl substituent or substituents is at least 7 and at least one such alkyl substituent is branched chain. Process of recovering copper and nickel from their aqueous solutions by the use of the new .beta.-diketones.

REFERENCES:
patent: 2313621 (1943-03-01), Bruson
patent: 2659711 (1953-11-01), Wilkins et al.
patent: 2864850 (1958-12-01), Westfahl
patent: 3047375 (1962-07-01), Pellegrini
patent: 3082071 (1963-03-01), Hartle et al.
patent: 3742062 (1973-06-01), Chappelow et al.
Hampton et al., J. Org. Chem., vol. 31, pp. 1035-1038 (1966).
Stary, The Solvent Extraction of Metal Chelates, pp. 51-79, (1965).

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