Certain 2-(pyridyl or thienyl)-1,3,4-oxadiazole-5-methylene-thio

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Phosphorus containing other than solely as part of an...

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514 92, 546 22, 548143, C07F 958, C07F 965, A01N 4340, A01N 4382

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active

046543309

ABSTRACT:
A compound of the formula ##STR1## wherein R is allyl, halocyclopropyl, C.sub.3 -C.sub.5 alkoxycarbonylmethyl, C.sub.7 -C.sub.9 aralkyl, styryl, phenyl, naphthyl, furanyl, pyridyl, thienyl, phenyl substituted with halogen, C.sub.1 -C.sub.4 alkyl, trihalomethyl, C.sub.1 -C.sub.4 alkoxy, trihalomethoxy, trihalomethylthio, C.sub.1 -C.sub.4 alkylthio, phenyl, phenoxy, cyano or nitro or C.sub.7 -C.sub.9 aralkyl substituted with halogen, C.sub.1 -C.sub.4 alkyl, trihalomethyl, C.sub.1 -C.sub.4 alkoxy, trihalomethoxy, trihalomethylthio, C.sub.1 -C.sub.4 alkylthio, phenyl, phenoxy, cyano or nitro; R.sup.1 is hydrogen, C.sub.1 -C.sub.3 alkyl, C.sub.7 -C.sub.9 aralkyl, phenyl, C.sub.7 -C.sub.9 aralkyl substituted with halogen, C.sub.1 -C.sub.4 alkyl, trihalomethyl, C.sub.1 -C.sub.4 alkoxy, trihalomethoxy, trihalomethylthio, C.sub.1 -C.sub.4 alkylthio, phenyl, phenoxy, cyano or nitro or phenyl substituted with halogen, C.sub.1 -C.sub.4 alkyl, trihalomethyl, C.sub.1 -C.sub.4 alkoxy, trihalomethoxy, trihalomethylthio, C.sub.1 -C.sub.4 alkylthio, phenyl, phenoxy, cyano or nitro, however, if R is substituted phenyl or substituted C.sub.7 -C.sub.9 aralkyl, then R.sup.1 cannot be hydrogen; R.sup.2 is C.sub.1 -C.sub.4 alkyl, however, if R or R.sup.1 is 4-chlorophenyl, R.sup.2 cannot be isopropyl; and X, Y and Z are the same or different and are oxygen or sulfur, is disclosed. A method is provided for protection against pests by employing a pesticidally effective amount of the compound above. A composition comprising the compound above and an inert carrier therefor, for pesticidal use, is also taught.
The disclosure also recites a compound of the formula ##STR2## where R and R.sup.1 have the meanings of the first mentioned compound. The compound, effective as an intermediate in the synthesis of the above compound, is produced by the reaction of a compound of the formula ##STR3## where R has the meanings given above with a compound of the formula

REFERENCES:
patent: 3432519 (1969-03-01), Metivier et al.
patent: 3502668 (1970-03-01), Palazzo et al.
patent: 3690858 (1972-09-01), Dahle et al.
Suzuki et al., Chem. Abstracts, vol. 86, No. 9, Abst. No. 55451d, Feb. 28, 1977.

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