Ceric hydrocarbyloxy nitrates and their use in organic synthesis

Details Ceric hydrocarbyloxy nitrates and their use in organic synthesis Ceric hydrocarbyloxy nitrates and their use in organic synthesis

1987-11-12

1990-04-24

Hunt, Brooks H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Rare earth containing

C07F 500

Patent

active

049202049

ABSTRACT:
Ceric hydrocarbyloxy nitrates having the general formula: ##STR1## are obtained by reaction of ceric ammonium nitrate with x moles of ammonia and an aliphatic, cycloaliphatic or aromatic alcohol having from two to twenty carbon atoms, and are useful in the preparation of ceric hydrocarbyl oxides difficult or expensive of access by other routes, and in synthesis of other organic ceric compounds.

REFERENCES:
patent: 4489000 (1984-12-01), Gradeff et al.
Bradley et al., J.C.S. (1956), pp. 2260-2264.
Gradeff et al., Inorg. Chem., 24 (1985), p. 1110.
Gradeff et al., J. of the Less-Common Metals, 126 (1986), pp. 335-338.

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