Coating processes – Coating by vapor – gas – or smoke – Metal coating
Reexamination Certificate
2001-06-20
2003-08-05
Meeks, Timothy (Department: 1762)
Coating processes
Coating by vapor, gas, or smoke
Metal coating
C427S597000, C427S255400, C427S405000, C427S437000, C427S438000, C427S383700, C205S224000, C205S228000, C205S264000, C205S271000, C416S24400R, C416S21900R, C416S221000
Reexamination Certificate
active
06602548
ABSTRACT:
BACKGROUND OF THE INVENTION
The present invention generally relates to turbine blades and, more particularly, to compliant layers employed to attach turbine blades to a disk.
Gas turbine power plants are used as the primary propulsive power source for aircraft, in the forms of jet engines and turboprop engines, as auxiliary power sources for driving air compressors, hydraulic pumps, etc. on aircraft, and as stationary power supplies such as backup electrical generators for hospitals and the like. The same basic power generation principles apply for all of these types of gas turbine power plants. Compressed air is mixed with fuel and burned, and the expanding hot combustion gases are directed against stationary turbine vanes in the engine. The vanes turn the high velocity gas flow partially sideways to impinge upon turbine blades mounted on a turbine disk or wheel that is free to rotate.
The force of the impinging gas causes the turbine disk to spin at high speed. Jet propulsion engines use this power to draw more into the engine and then high velocity combustion gas is passed out the aft end of the gas turbine, creating forward thrust. Other engines use this power to turn a propeller or an electric generator.
The turbine blades and vanes lie at the heart of the power plant, and it is well established that, in most cases, they are one of the limiting factors in achieving improved power plant efficiency. In particular, because they are subjected to high heat and stress loadings as they are rotated and impacted by the hot gas, there is a continuing effort to identify improvements to the construction and/or design of turbine blades to achieve higher performance.
Much research and engineering has been directed to the problem of improved turbine blade materials. The earliest turbine blades were made of simple cast alloys having relatively low maximum operating temperatures. The alloy materials have been significantly improved over a period of years, resulting in various types of nickel-based and cobalt-based superalloys that are in use today.
Ceramic blades (Si3N4) are used when a turbine needs to be run at elevated temperatures to improve the efficiency and performance of turbine engines. However, ceramic blades need to be inserted into metallic turbine disks. Because ceramic blades are susceptible to fracture by local point loading, a compliant layer is needed to redistribute the ceramic blade loading. As the ceramic is operated at high temperature and high speeds in a turbine, a compliant layer is needed which supports the loading without extrusion or creeping and yet plastic or soft enough to redistribute the loading at the ceramic compliant layer interface. At each engine cycle, the blade must part from the metallic turbine disk to accommodate the thermal expansion differences between ceramic and metal to prevent crushing of the blade root.
U.S. Pat. No. 6,132,175 for Compliant Sleeve For Ceramic Turbine Blades discloses the use of a compliant layer fabricated from a cobalt-based low temperature capable superalloy which is bonded to a thin layer of nickel and platinum. The structure is oxidized to form a NiO surface, which contacts the ceramic blade. The compliant layer is lubricated with BN (Hexagonal Boron nitride) and sputtered gold.
U.S. Pat. No. 6,127,048 for Article Of Manufacture Having A Metal Substrate With An Oxide Layer And An Improved Anchoring Layer And Method Of Bonding The Same describes the formation of anchored thermal barrier coating on ceramic blades. It uses an anchoring layer primarily made from ternary oxides. The '048 patent does not relate to a compliant layer. Essentially, the blades which need to be protected from thermal conditions of the engine are coated with thermal barrier layers. This patent suggests that intermediate ternary oxides improve the bonding of the zirconia thermal barrier coating. The disclosed blade has coatings of low thermal conductivity oxides that do not provide the required compliance and durability on repeated cycling (both thermal and mechanical movement) needed for the present application.
U.S. Pat. No. 6,066,405 for Nickel-Base Superalloy Having An Optimized Platinum-Aluminide Coating uses a platinum-aluminum coating over metallic blades and may use a ceramic thermal barrier coating over the blade. This patent is similar to the previous patent disclosing a thermal barrier coating for metallic turbine blades. This has nothing to do with compliant layers for ceramic blade attachment. Platinum aluminide is an intermetallic compound and lacks the ductility of platinum and, thus, will not provide the required compliance and load distribution characteristics needed to support a ceramic blade. The ceramic thermal barrier coating is also very hard and if it comes in contact with a ceramic blade, it will shatter it due to localized loading.
U.S. Pat. No. 5,712,050 for Superalloy Component With Dispersion-Containing Protective Coating describes a coating for a superalloy article which is a nickel based superalloy containing dispersoids of oxides of yttrium, hafnium and or a rare earth. The coating protects the superalloy body from oxidation, fatigue, etc. This patent describes a protective coating on superalloy articles such as blades and has nothing to do with compliant layers. If a similar coating were used for compliant layers, it would not work because the nickel based superalloy with dispersoids lacks the compliance and the hard particles will produce localized contact on the ceramic blade creating point loading and fracture.
What is still needed is a compliant layer coating for a ceramic turbine blade wherein the layer is capable of operating at higher temperatures and levels of stress in an oxidizing environment.
SUMMARY OF THE INVENTION
The present invention resides in the use of a nickel based single crystal compliant layer on a ceramic blade, which has the capability to sustain the high stresses at high operating temperatures, but the properties of such a layer are easily degraded by contamination as well as nucleation of secondary grains. The high stresses applied at high temperature can easily squeeze out the thin layers of soft metals such as platinum and nickel. When this happens, the nickel oxide layer generated will break and disappear on subsequent loading and unloading cycles. The invention exploits the discovery that layers on nickel and platinum bonded on a single crystal superalloy over a sputtered gold-chromium layer can indeed support the high stress levels at elevated temperature without extrusion of the soft platinum or nickel layer and without destruction of an NiO compliant surface. The compliant layers have survived stress and temperature conditions without failure to the ceramic blade and the system can be stressed/heated and unloaded/cooled repeatedly without damage to the ceramic blades.
A high strength superalloy is employed due to its single crystal nature and a coating is used which does not degrade the single crystal alloy, yet provides sufficient compliance to support the ceramic blade under conditions of high stress (such as about 50 Ksi to 100 Ksi) and high temperature (such as about 760° C. to 875° C.). The blade is released without bond formation on each cycle so that, during cooling, the blade is not crushed by the dove tail slot due to the large thermal expansion coefficient of the metallic disk alloy compared to the silicon nitride ceramic blade.
This invention may use a single crystal nickel base superalloy (e.g., SC180) which has high strength properties (e.g., about 60 Ksi to 160 Ksi yield depending on orientation) at elevated temperature (e.g., about 760° C. to 875° C.). Thin layers of chromium followed by gold are e-beam evaporated on one side of a polished surface of the alloy. Pure nickel is electroplated over this e-beam gold-chromium layer. Platinum is either electroplated or plated electrolessly over the nickel layer. The structure is annealed in vacuum or inert atmosphere to allow the diffusion of gold-chromium alloy into the superalloy and permit the nickel layer and diffusi
Eagan Margaret
Kozlov Alexander S.
Narasimhan Dave
Ortiz Milton
Desmond, Esq. Robert
Honeywell International , Inc.
Meeks Timothy
LandOfFree
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