Stock material or miscellaneous articles – Structurally defined web or sheet – Discontinuous or differential coating – impregnation or bond
Reexamination Certificate
2003-03-28
2004-04-27
Lam, Cathy (Department: 1775)
Stock material or miscellaneous articles
Structurally defined web or sheet
Discontinuous or differential coating, impregnation or bond
C174S255000, C174S264000
Reexamination Certificate
active
06726984
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates generally to a new ceramic structure and process thereof. Basically, the present invention relates to a structure and method for forming laminated structures and more particularly to a structure and method for fabricating multi-layer ceramic products using very thin green sheets and/or green sheets with very dense electrically conductive patterns on top of a stronger support sheet.
BACKGROUND OF THE INVENTION
Multi-layer ceramic (MLC) structures are used in the production of electronic substrates and devices. The MLCs can have various layering configurations. For example, a MLC circuit substrate may comprise patterned metal layers which act as electrical conductors sandwiched in between ceramic layers which act as a dielectric medium. For the purposes of interlayer interconnections, most of the ceramic layers have tiny holes or via holes. Prior to lamination, the via holes are filled with an electrically conductive paste, such as, a metallic paste, and sintered to form vias which provide the electrical connection between the layers. In addition, the MLC substrates may have termination pads for attaching semiconductor chips, connector leads, capacitors, resistors, to name a few.
Generally, conventional ceramic structures are formed from ceramic green sheets which are prepared from a slurry of ceramic particulate, thermoplastic polymer binders, plasticizers, and solvents. This composition is spread or cast into ceramic sheets or slips from which the solvents are subsequently volatilized to provide coherent and self-supporting flexible green sheets. After punching, metal paste screening, stacking and laminating, the green sheets are fired or sintered at temperatures sufficient to burn-off or remove the unwanted polymeric binder resin and sinter the ceramic particulate together into a densified ceramic substrate. The present invention is directed to the screening, stacking and lamination steps of this process.
In the MLC packaging industry it is very common to use green sheets of various thicknesses. The thicknesses can typically vary from 6 mils to 30 mils and in general the art of punching and metallizing these layers are well known. Green sheet thicknesses below 6 mils, in general, are very scarcely used. This is due to a variety of reasons, such as, for example, handling, screening and stacking of green sheets thinner than 6 mils pose tremendous challenges. In fact the use of one to two mils thick ceramic green sheets, which are punched and screened, using traditional MLC technology does not exist in the prior art.
Also, in the MLC packaging industry it is very common to use capacitor layers. The capacitance necessary in a package depends on the design and such capacitance is obtained by choosing proper dielectric layer thickness and metal area within a layer. The industry is always striving for higher capacitance and since the metal area is maxing out for a given substrate size it is necessary to use thinner dielectric layers between electrodes to obtain the required capacitance. For example, as a rule of thumb one could double the capacitance for a given dielectric system and electrode metal area by decreasing the dielectric layer thickness by half. Additionally the number of layers needed for capacitance in a package as well has been reduced by about 50 percent. The reduction in the number of layers is desirable, as it reduces the cost and the process of making the substrate.
The term thin sheet or layer as used herein means that the thickness of the sheet can be anywhere from about 0.5 mil to about 6.0 mils. Production level screening and stacking of thin sheets is not possible with the current technology as the thin sheets tend to shrink a lot and they also tend to distort during the process.
U.S. Pat. No. 5,176,772 (Ohtaki) and U.S. Pat. No. 5,300,163 (Ohtaki), addresses a method of forming a thin sintered ceramic board by laminating punched and screened green tapes on a presintered ceramic body and sintering the assembly to obtain a flat board. This method essentially enables one to obtain a flat laminate. But, with ceramic substrates with materials like alumina and aluminum nitride there is typically a 14 to 20 percent X-Y shrinkage. So there will be delamination and distortion involved in sintering due to presintered base. Furthermore, one needs to handle these sheets through screening in free standing state.
U.S. Pat. No. 5,368,667 (Minh), teaches preparing a multi-layer capacitor which is one to two mils thick by extruding a thick dielectric layer and a metal containing layer through a roll laminator. This approach is good for using a thin layer having the blanket metallurgy. But in almost all multi-layer ceramic packages, one needs to have vias for electrical connectivity. However, this patent does not address the problem of handling the thin sheets in via filling and stacking.
U.S. Pat. No. 5,480,503 (Casey), teaches releasably-supporting the thin green sheets on a temporary carrier support having an ablatable release layer over a patterned conductive layer, and filling the vias with conductive metal paste, whereby the thin green sheets are supported against warpage and distortion. The supported green sheets are formed as single layers, pairs and stacks thereof, and separated from temporary support for use. The suggested temporary support is a glass plate. The metallization technique is CVD type plating and in the process has to use non-ablatable and ablatable films on the green sheet. These films inherently will distort the green sheet during temperature and pressure processing. Furthermore, the non-ablatable film stays with every single green sheet layer and will create delamination and density difference in sintering.
U.S. Pat. No. 5,976,286 (Natarajan), assigned to International Business Machines Corporation, Armonk, N.Y., USA, the disclosure of which is incorporated herein by reference, teaches the use of at least one thin green sheet and a thick green sheet for fabricating a multi-density sub-structure.
The structure and method of the present invention enables the screening, stacking and handling of very thin green sheets and/or green sheets with very dense metallized patterns in the manufacture of multi-layer ceramic packages. With the preferred embodiment, thin green sheets were tacked and bonded to a support sheet, such as, a thin metal or a like carrier, to form a sub-structure which yields excellent stability in screening and enables excellent handling and alignment in stacking. The green sheet may have electrically conductive features within them, such as, a via, or over them, such as, a line, cap, to name a few.
PURPOSES AND SUMMARY OF THE INVENTION
Bearing in mind the problems and deficiencies of the prior art it is therefore one purpose of the present invention to provide a novel method and structure for producing metallized thin green sheets including sub-structures in multi-layer ceramic packages as capacitor layers or with fine line patterned conductive metal layers
Another purpose of this invention is to provide a structure and a method that will ensure multiple thin layers in a multilayer ceramic package.
Still another purpose of the present invention is to provide a structure and method that will ensure higher capacitance in a multi-layer ceramic package.
Yet another purpose of the present invention is to have a structure and a method for fine line pattern using thin green sheets in multi-layer ceramic packages.
Still yet another purpose of the present invention is to provide a structure and a method for metallizing a thin green sheet without any detrimental distortion.
Still another purpose of the present invention is to have a structure and a method that will ensure handling of thin green sheets for multi-layer ceramic packages.
It is another purpose of the invention to have a structure and a method that produces a multilayer ceramic package that is predictable and repeatable.
Another purpose of the present invention is to laminate several stacked green sheets to produce sub-structures.
O
Knickerbocker John U.
Natarajan Govindarajan
Pasco Robert W.
Bilak Mark
International Business Machines - Corporation
Lam Cathy
Pepper Margaret A.
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