Ceramic-metal articles and methods of manufacture

Specialized metallurgical processes – compositions for use therei – Compositions – Consolidated metal powder compositions

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75237, 75238, 75239, 75240, 75241, 75242, 75244, 428547, 428610, C22C 2902

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active

050890476

ABSTRACT:
A dense cermet article including about 80-95% by volume of a granular hard phase and about 5-20% by volume of a metal phase. The granular hard phase consists essentially of a ceramic material selected from the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, carboxynitrides, and borides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, boron, and mixtures thereof. The metal phase consists essentially of a combination of nickel and aluminum having a weight ratio of nickel to aluminum of from about 90:10 to about 70:30 and 0-5% by weight of an additive selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, cobalt, boron, or carbon, or combinations thereof. In the preferred metal phase, an amount of about 15-80% by volume of the metal phase component exhibits a Ni.sub.3 Al ordered crystal structure. The article may be produced by presintering the hard phase - metal phase component mixture in a vacuum or inert atmosphere at about 1475.degree.-1675.degree. C., then densifying by hot isostatic pressing at a temperature of about 1575.degree.-1675.degree. C., in an inert atmosphere, and at about 34-207 MPa pressure. Limiting the presintering temperature to 1475.degree.-1575.degree. C. and keeping the presintering temperature at least 50.degree. C. below the not pressing temperature produces an article of gradated hardness, harder at the surface than at the core.

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S. Sridharan et al., "Investigations Within the Quarternary System Titanium-Nickel-Aluminum-Carbon", Monatshefte fur Chemie, 114, 127-135 (1983).
A. V. Tumanov et al., "Wetting of TiC-WC System Carbides with Molten Ni.sub.3 Al", pp. 428-430 of translation from Poroshkovaya Metallurgiya, 5(281), pp. 83-86 (May 1986).

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