Specialized metallurgical processes – compositions for use therei – Compositions – Consolidated metal powder compositions
Patent
1990-12-20
1991-10-01
Stoll, Robert L.
Specialized metallurgical processes, compositions for use therei
Compositions
Consolidated metal powder compositions
75232, 75233, 75234, 75235, 75237, 75238, 75240, 75241, 75239, 75242, 75244, C22C 2902
Patent
active
050530747
ABSTRACT:
A dense cermet article including about 80-90% by volume of a granular hard phase and about 5-20% by volume of a metal phase. The hard phase is a carbide, nitride, carbonitride, oxycarbide, oxynitride, or carboxynitride of a cubic solid solution selected from W-Ti, W-Hf, W-Nb, W-Ta, Zr-Ti, Hf-Ti, Hf-Zr, V-Ti, Nb-Ti, Ta-Ti, or Mo-Ti. The metal phase consists essentially of a combination of nickel and aluminum having a ratio of nickel to aluminum of from about 90:10 to about 70:30 by weight, and 0-5% by weight of an additive selected from titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, cobalt, boron, and/or carbon. The preferred hard phase is a cubic solid solution of tungsten and titanium. In the preferred metal phase, an amount of about 15-80% by volume of the metal phase component exhibits a Ni.sub.3 Al ordered crystal structure. The article may be produced by presintering the hard phase - metal phase component mixture in a vacuum or inert atmosphere at about 1475.degree.-1675.degree. C., then densifying by hot isostatic pressing at a temperature of about 1575.degree.-1675.degree. C., in an inert atmosphere, and at about 34-207 MPa pressure. Limiting the presintering temperature to 1475.degree.-1575.degree. C. and keeping the presintering temperature at least 50.degree. C. below the hot pressing temperature produces an article of gradated hardness, harder at the surface than at the core.
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Buljan Sergej T.
Lingertat Helmut
Wayne Steven F.
Craig Frances P.
GTE Laboratories Incorporated
Nigohosian Leon
Stoll Robert L.
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