Ceramic composition

Superconductor technology: apparatus – material – process – High temperature – per se – Having tc greater than or equal to 150 k

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

505738, H01L 3912

Patent

active

050011090

ABSTRACT:
Improved process for making Bi-Pb-Sb-Sr-Ca-Cu oxide superconductors. A solution of the nitrates of Bi, Pb, Sr, Ca, and Cu is reacted with a quaternary ammonium carbonate in a dispersion (heel) of Sb.sub.2 O.sub.5. Carbonates of Bi, Pb, Sr, Ca, and Cu precipitate homogeneously on the Sb.sub.2 O.sub.5 particles. Solids are recovered, dried, and heated to make a superconductor. The method minimizes handling toxic antimony compounds and reduces introduction of contaminants. Novel compositions result.

REFERENCES:
patent: 4839339 (1989-04-01), Bunker et al.
patent: 4880771 (1989-04-01), Cava et al.
patent: 4894361 (1989-06-01), Subramanian
Hongbao, "Superconducting Properties in (Bi.sub.2-x-y Pb.sub.x Sb.sub.y)Sr.sub.2 Ca.sub.2 CuO.sub.z System", 10/15/88 submitted to Physica Co, Preprint.
Hongbao "Zero Resistance at B2K in the Multiphase System of BiPbSbSrCa-CuO etc.".
Hongbao "Superconducting Transition Above 150K in BiSbSrCaCuO System" preprint 12/5/88 Physica C.
Bednorz & Muller, Possible High Tc Superconductivity in the Ba-La-Cu-O System, Zeit. Phys. B., 64, 189-193 (1986).
Subramanian et al., A New High Temperature Superconductor: Bi.sub.2 Sr.sub.3-x Ca.sub.x Cu.sub.2 O.sub.8+y', Science, 239, 1015 (1988).
Gao et al., Bulk Superconductivity in T1.sub.2 CaBa.sub.2 Cu.sub.2 O.sub.8+.delta., Nature, 332, 623-624 (1988).
Wang et al., Comparison of Carbonate, Citrate, and Oxalate Chemical Routes to the High-Tc Metal Oxide Superconductors La.sub.2-x Sr CuO.sub.4, Inorg. Chem. 26, 1474-1476 (1987).
Mao, X. et al., The Influence of Pb Composition on the Upper Critical Magnetic Field of Bi.sub.1.9-x Pb.sub.x Sb.sub.0.1 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.y.
Liu, H. et al., Zero Resistance at 132.degree. K. in the Multiphase System of Bi.sub.1.9-x Pb.sub.x Sb.sub.0.1 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.y. (Undated Preprint.).
Liu, H. et al., Superconducting Transition Above 160 .degree. K. in Bi-Pb-Sb-Sr-Ca-Cu-O System. (Undated Preprint.).
Liu, H. et al., Superconducting Properties in (Bi.sub.2-x-y Pb.sub.x Sb.sub.y)Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.z (x=0, 0.1, 0.3, 0.5; y=0, 0.1). (Undated preprint.).
Liu, H. et al., The Superconducting Properties in Bi.sub.2-x Sb.sub.x Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.4 Compounds, (x=0.05, 0.1, 0.15, 0.2). Physica C, 156, 804-806 (1988).
Voigt, J. A. et al., A Hydroxycarbonate Route to Superconductor Precursor Powders, paper available at Fall Meeting of Materials Research Soc., Boston, late Nov., 1987 (Sandia.).
Kaneko et al., "On the Precipitation Method for the Preparation of High Tc M-X-Cu-O (M=Ba, Sr, X=La, Y) System," Japanese Journal of Applied Physics, vol. 26, No. 5, May, 1987, pp. L734-L735.
Fujiki et al., "Preparation of High Tc-Y-Ba-Cu-O Superconductor Using Colloidal Methods," Jul., 1987, Japanese Journal of Applied Physics, pp. L 1159-1160.
Two Declarations under 37 CFR 1.131 from file of Bunker U.S. Pat. No. 4,839,339.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Ceramic composition does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Ceramic composition, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Ceramic composition will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2010121

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.