Ceramic composition

Superconductor technology: apparatus – material – process – High temperature – per se – Having tc greater than or equal to 150 k

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

505738, 505783, H01L 3912

Patent

active

050029266

ABSTRACT:
Improved process for making Tl-Ca-Ba-Cu oxide superconductors. A solution of the nitrated of Ca, Ba, and Cu is reacted with a quaternary ammonium carbonate in a slurry (heel) of Tl.sub.2 O.sub.3. Carbonates of Ca, Ba, and Cu precipitate homogeneously on the Tl.sub.2 O.sub.3 particles. Solids are recovered, dried, and heated to make a superconductor. The method minimizes introdution of contaminants. Novel compositions result.

REFERENCES:
patent: 4804649 (1989-07-01), Sherif
patent: 4839339 (1989-06-01), Bunker et al.
patent: 4870052 (1989-09-01), Engler et al.
patent: 4880771 (1989-11-01), Cava et al.
patent: 4894361 (1989-01-01), Subramanian
Hazen et al., "100K Superconducting Phases in the Tl-Ca-Ba-CuO-System", Physical Review Letters, vol. 60, No. 16, Apr. 1988, pp. 1657-1660.
Shenh et al., "Bulk Superconductivity at 120K in the Tl-Ca/Ba-Cu-O System", Letters to Nature, Vol. 332, 10 Mar. 1988, pp. 138-139.
Kaneko et al., "On the Precipitation Method for the Preparation of High Tc M-X-Cu-O (M=Ba, Sr, X=La, Y) System," Japanese Journal of Applied Physics, vol. 26, No. 5, May, 1987, pp. L734-L735.
Fujiki et al., "Preparation of High Tc-Y-Ba-Cu-O Superconductor Using Colloidal Methods," Jul., 1987, Japanese Journal of Applied Physics, pp. L 1159-1160.
Wu et al., Superconductivity at 93K in a New Mixed Phase Y-Ba-Cu-O Compound System at Ambient Pressure, Phys. Rev. Lett., 58, 908-910 (2 Mar. 1987).
Engler et al., Superconductivity Above Liquid Nitrogen Temperature: Preparation and Properties of a Family of Perovskite-Based Supercondustors, J. Am. Chem. Soc., 109, 2848-2849 (1987).
Wang et al., Comparison of Carbonate, Citrate, and Oxalate Chemical Routes to the High-Tc Metal Oxide Superconductors La.sub.2-x Sr.sub.x CuO.sub.4, Inorg. Chem., 26, 1474-1476 (1987).
Bednorz, J. G. et al., Possible High Tc Superconductivity in the Ba-La-Cu-O System, Zeit. Phys. B., 64, 189-193 (1986), (English translation.).
Sheng, Z. Z. et al., Superconductivity in the Rare Earth-Free Tl-Ba-Cu-O System above Liquid Nitrogen Temp, Nature, 332, 55-58 (1988).
"Nota Bene" in High Tc Update, vol. 2, No. 6, p. 1 Mar. 15, 1988.
Subramanian, M. A. et al., Science, 239, p. 1015, Feb. 20, 1988.
Gao, L. et al., Nature, 332, 623-624 (1988).
Michel, C. et al., Oxygen Intercalation in Mixed Valence Copper Oxides Relates to the Perovskites, Rev. de Chim. Minerale, t. 21, 407-425 (1984).
Dagani, R., New Class of Superconductors Pushing Temperatures Higher, C & EN, May 16, 1988, pp. 24-29.
Hazen, R. M., Perovskites, Sci. Amer., pp. 74-81, Jun. 1988.
Voigt, J. A. et al., A Hydroxycarbonate Route to Superconductor Precursor Powders, paper available at Fall meeting of Materials Research Society, Boston, late Nov. 1987.
Sheng, Z. Z., et al., Superconductivity Above 90K in the Tl-Ba-Cu-O System, Phys. Rev. Lett. (available as copy of typescript).
Hermann, A. M. et al., Melt-Processible Rare Earth-Ba-Cu-O Superconductors Based on Molten Ba-Cu Oxides, Appl. Phys. Lett., 51, 1854-1856 (Nov. 30, 1987).
Cava, R. J. eta l., Bulk Superconductivity at 91K in Single-Phase Oxygen-Deficient Peroskite Ba.sub.2 YCu.sub.3 O.sub.9-.delta., Phys. Rev. Lett., 58, 1676-1679 (20 Apr. 1987).
Nguyen, Ninh et al., Oxygen Defect K2NiF4-Type Oxides: The Compounds La.sub.2-x Sr.sub.x CuO.sub.x-x/2+.delta., Jour. Solid State Chem., 39, 120-127 (1981).
Nguyen, N. et al., Oxydes Ternaires de Cuivre a Valence Mixte de Type K2NiF4 Deficitaires en Oxygene: Evolution Progressive d'un Etat Semi-conducteur vers un Etat Semi-metallique Des Oxydes La.sub.2-x Sr.sub.x CuO.sub.4-x/2+.delta., J. Phys. Chem. Solids, 44, 389-400 (1983).
Shaplygin, I. S. et al., Preparation and Properties of the Compounds Ln.sub.2 CuO.sub.4 (Ln=La, Pr, Nd, Sm, Eu, Gd) and Some of Their Solid Solutions, Russ. J. Inorg. Chem., 24, 1478-1485 (1979).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Ceramic composition does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Ceramic composition, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Ceramic composition will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-617201

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.