Ceramic coating system or water oxidation environments

Liquid purification or separation – Processes – Chemical treatment

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210762, 422 7, 422240, C02F 172

Patent

active

055453376

ABSTRACT:
A process for water oxidation of combustible materials in which during at least a part of the oxidation corrosive material is present and makes contact with at least a portion of the apparatus over a contact area on the apparatus. At least a portion of the contact surface area comprises titanium dioxide coated onto a titanium metal substrate. Such ceramic composites have been found to be highly resistant to environments encountered in the process of supercritical water oxidation. Such environments typically contain greater than 50 mole percent water, together with oxygen, carbon dioxide, and a wide range of acids, bases, and salts. Pressures are typically about 27.5 to about 1000 bar while temperatures range as high as 700.degree. C. The ceramic composites are also resistant to degradation mechanisms caused by thermal stresses.

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Hazlebeck et al., "Supercritical Water Oxidation of Chemical Agents, Solid Propellants, and other DOD Hazardous Wastes", General Atomics, Mar. 1993.
Downey et al., "Corrosion and Chemical Agent Destruction Investigations of the Supercritical Water Oxidation of Hazardous Military Wastes", Prepared for Presentation at the AICHE 1994 Annual Meeting; Reactions in Supercritical Fluids, Nov 1994.

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