Cementing wells with crack and shatter resistant cement

Wells – Processes – Cementing – plugging or consolidating

Reexamination Certificate

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Details

C106S711000

Reexamination Certificate

active

06308777

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates generally to cementing subterranean zones penetrated by well bores, and more particularly, to such methods whereby cement compositions which are crack and shatter resistant are utilized.
2. Descrintion of the Prior Art
Hydraulic cement compositions are commonly utilized in subterranean well completion and remedial operations. For example, hydraulic cement compositions are used in primary cementing operations whereby pipe strings such as casings and liners are cemented in well bores. In performing primary cementing, a hydraulic cement composition is pumped into the annular space between the walls of a well bore and the exterior surfaces of a pipe string disposed therein. The cement composition is permitted to set in the annular space thereby forming an annular sheath of hard substantially impermeable cement therein. The cement sheath physically supports and positions the pipe string in the well bore and bonds the exterior surfaces of the pipe string to the walls of the well bore whereby the undesirable migration of fluids between zones or formations penetrated by the well bore is prevented.
Multi-lateral wells have recently been developed which include vertical or deviated principal well bores having one or more ancillary laterally extending well bores connected thereto. Drilling and completion equipment is available which allows multiple laterals to be drilled from a principal cased and cemented well bore. Each of the lateral well bores can include a liner cemented therein which is tied into the principal well bore. The lateral well bores can be drilled into predetermined producingformations or zones at any time in the productive life cycle of the well.
In both conventional wells having single well bores and multi-lateral wells having several bores, the cement compositions utilized for cementing casings or liners in the well bores must have sufficient ductility and toughness to resist cracking or shattering as a result of pipe movements, impacts and/or shocks subsequently generated by drilling and other well operations. Set cement in wells, and particularly, a set cement. Sheath in the annulus between a pipe string and the walls of a well bore often fails by cracking or shattering during perforating and/or drilling operations. When the set cement cracks or shatters, rubble is often produced in the well or annulus.
Various types of fibers have been utilized in construction cement compositions heretofore including fibers formed of glass, steel, graphite, polyesters, polyamides and polyolefins. Polyolefin fibers are generally the most preferred in that they are readily available, are low in cost and have high resistance to corrosion and degradation. Fibrillated net-shaped polyolefin fibers are particularly suitable for use in cement compositions because they resist being pulled out of the set cement. The fibers fimction to control shrinkage cracking in the early stages of the cement setting process, and after setting, the fibers provide ductility and toughness to the cement composition whereby it resists cracking or shattering. When cracking or shattering does occur, the fibers hold the cracked or shattered set cement together and prevent the formation of rubble.
A problem heretofore experienced in the use of fibers in well cement compositions is that the fibers are hydrophobic and are difficult to dry blend with cement. The fibers agglomerate in the dry cement when it is conveyed causing plugging to occur, and when the cement and fibers are combined with mixing water, the fibers form mats which prevent their dispersion into and throughout the cement slurry. The lack of dispersion of the fibers in the cement slurry make it difficult to pump.
Thus, there are needs for improved well cement compositions and methods wherein the cement compositions contain fibrillated fibers which can be easily mixed and conveyed with dry cement and subsequently dispersed in the aqueous cement slurries formed.
SUMMARY OF THE INVENTION
The present invention provides improved cement compositions and methods of cementing a subterranean zone which meet the needs described above and overcome the deficiencies of the prior art. The methods of the invention are basically comprised of the steps of introducing a crack and shatter resistant cement composition into a subterranean zone to be cemented and allowing the cement composition to set therein. The crack and shatter resistant cement compositions utilized in accordance with this invention are basically comprised of a hydraulic cement, sufficient hydrophilic fibers to make the cement composition crack and shatter resistant upon setting and sufficient water to form a pumpable slurry of the cement and fibers. The hydrophilic fibers utilized in accordance with this invention are preferably hydrophilic fibrillated polyolefin fibers.
The methods of this invention are particularly suitable for cementing a pipe string such as casing or a liner in a well bore whereby the set cement can withstand the formation of perforations therein as well as other impacts and shocks subsequently generated by drilling and other well operations without cracking or shattering and forming rubble. Such methods are basically comprised of the following steps. A crack and shatter resistant cement composition of this invention is pumped into the annulus between the pipe string and the walls of the well bore. The cement composition is then allowed to set into a hard crack and shatter resistant impermeable mass having ductility and toughness.
It is, therefore, a general object of the present invention to provide improved cement compositions and methods of cementing subterranean zones penetrated by well bores using the cement compositions.
Other and further objects, features and advantages of the present invention will be readily apparent to those skilled in the art upon a reading of the description of preferred embodiments which follows.
DESCRIPTION Of PREFERRED EMBODIMENTS
The present invention provides improved crack and shatter resistant cement compositions and methods of cementing subterranean zones using the compositions. The improved crack and shatter resistant cement compositions are basically comprised of a hydraulic cement, sufficient hydrophilic fibers to make the cement composition crack and shatter resistant upon setting and sufficient water to form a pumpable slurry of the cement and fibers. The methods are basically comprised of the steps of introducing a crack and shatter resistant cement composition of this invention into the zone by way of the well bore and then allowing the cement composition to set in the zone.
The term “crack and shatter resistant cement composition” is used herein to mean a cement composition that sets into a hard impermeable mass having ductility and toughness and that resists cracking and/or shattering as a result of perforating operations, pipe movements, impacts, shocks and the like. If cracking or shattering does occur, the pieces formed are held together by the hydrophilic fibers in the cement composition.
While the cement compositions and methods of this invention are useful in a variety of well completion and remedial operations, they are particularly useful in primary cementing, i.e., cementing casings and liners in well bores. The crack and shatter resistant cement compositions of this invention are readily and easily prepared without the conveying, mixing, fiber dispersal and pumping problems encountered heretofore.
A variety of hydraulic cements can be utilized in the crack and shatter resistant cement compositions of this invention including those comprised of calcium, aluminum, silicon, oxygen and/or sulfur which set and harden by reaction with water. Such hydraulic cements include Portland cements, pozzolana cements, gypsum cements, high aluminum content cements, silica cements and high alkalinity cements. Portland cements are generally preferred for use in accordance with the present invention. Portland cements of the types defined and described in the
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