Cellulose products treated with isocyanate compositions

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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229100, 229939, 427391, 427392, 427393, 427428, 428264, 428274, 428378, 428393, 428396, 428533, 428534, 428535, 4285371, 4285375, 527103, 527301, 524 35, 524311, 524312, 524589, 524773, 524871, C08K 510, C08K 5101, C08K 511, B65D 2500, B65D 2534, B65D 500, C08G 1802, B32B 2906

Patent

active

055809227

ABSTRACT:
The invention is directed to a composition of matter useful as a paper impregnant, to the method of its use, and to the products produced by the method. Poly (diphenylmethane diisocyanate) or PMDI has been used in the past as a paper impregnant with or without propylene carbonate as a diluent. These products have generally required pressing under high pressures and at elevated temperatures. It has now been found that triacetin and/or triethyl citrate in usages up to about 20% of PMDI give superior performance in impregnated products. The modified PMDI will cure at essentially ambient conditions in times as short as 1-2 days to insoluble polyureas with low residual amounts of isocyanates and reaction byproducts such as 4,4'-diaminodiphenylmethane. The treated papers can be used in applications of which skins for sandwich panels and high strength corrugated board would be exemplary.

REFERENCES:
patent: 5008359 (1991-04-01), Hunter
patent: 5041517 (1991-08-01), Vu et al.
patent: 5104086 (1992-08-01), Hunter et al.
patent: 5130205 (1992-07-01), Vu et al.
patent: 5220760 (1993-06-01), Dimakis
patent: 5280097 (1994-01-01), Hunter et al.
patent: 5292391 (1994-03-01), Wallick
patent: 5332458 (1994-07-01), Wallick
patent: 5345738 (1994-09-01), Dimakis
patent: 5352709 (1994-10-01), Tarrant et al.

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