Cellulose ester compositions and shaped articles

Stock material or miscellaneous articles – Web or sheet containing structurally defined element or... – Including a second component containing structurally defined...

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4282921, 442181, 442327, 524 39, B32B 516

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058042962

ABSTRACT:
A composition comprises a cellulose acetate or other cellulose ester, and an anatase-type titanium oxide having (1) a specific surface area of not less than 30 m.sup.2 /g, (2) a primary particle size of 0.001 to 0.07 .mu.m, or (3) a specific surface area of not less than 30 m.sup.2 /g and a primary particle size of 0.001 to 0.07 .mu.m. For improving the photodegradability and the dispersibility, the surface of the titanium oxide may be treated with a phosphoric acid salt or other phosphorus compound, a polyhydric alcohol, an amino acid or others. Use of a low-substituted cellulose ester with an average substitution degree not exceeding 2.15 insures high biodegradability. The composition may further contain a plasticizer and/or an aliphatic polyester, a biodegradation accelerator (e.g. organic acids or esters thereof). The degradable cellulose ester composition is highly photodegradable and moldable and hence useful for the manufacture of various articles.

REFERENCES:
patent: 3669896 (1972-06-01), Preininger et al.
patent: 4022632 (1977-05-01), Newland et al.
patent: 4073764 (1978-02-01), Hemmerich et al.
patent: 4443535 (1984-04-01), Kiritani et al.
patent: 5242880 (1993-09-01), Irick, Jr.

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