Cationic polymerization of 1-olefins

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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C07C 318

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active

046058087

ABSTRACT:
This invention relates to a process for producing polyisobutene which has at least 70% of its unsaturation in the terminal position. The process uses a complex of boron trifluoride and alcohol as catalyst and a contact time of at least 8 minutes. The feature of the process is its ability to use longer contact times than used hitherto thereby facilitating its commercial operation and improving the control of such an operation. The high terminal unsaturation improves the reactivity of the polymer.

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