Cathode preparation method for molten carbonate fuel cell

Metal working – Method of mechanical manufacture – Electrical device making

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429223, 429 45, H01M 600

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active

047215135

ABSTRACT:
A method of preparing a porous cathode structure for use in a molten carbonate fuel cell begins by providing a porous integral plaque of sintered nickel oxide particles. The nickel oxide plaque can be obtained by oxidizing a sintered plaque of nickel metal or by compacting and sintering finely divided nickel oxide particles to the desired pore structure. The porous sintered nickel oxide plaque is contacted with a lithium salt for a sufficient time to lithiate the nickel oxide structure and thus enhance its electronic conductivity. The lithiation can be carried out either within an operating fuel cell or prior to assembling the plaque as a cathode within the fuel cell.

REFERENCES:
patent: 4115632 (1978-09-01), Kinoshita et al.
patent: 4251600 (1981-02-01), Sim et al.
patent: 4308299 (1981-12-01), Arendt
patent: 4410607 (1983-10-01), Arons et al.
Development of Molten Carbonate Fuel Cell Power Plant, DOE/ET/17019-2, Quarterly Tech. Progress Report, May 1-Jul. 31, 1980; pp. 75-78.
Development of Molten Carbonate Fuel Cell Power Plant Tech., DOE/ET/15440-2, Quarterly Technical Progress Report, No. 2, Jan. 1-Mar. 30, 1980, pp. 2-18 & 2-19.
Fuel Cell Research of Second Generation Molten-Carbonate Systems, San-11276-4, Final Report, Oct. 1, '78-Jan. 31, 1980; pp. 1-59 & 1-61.
Development & Testing of Alternative Fuel Cell Components, UAC-47344, Paper for Presentation at National Fuel Cell Seminar, 6/23-26, 1981.

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