Cathode composition for solid oxide fuel cell

Chemistry: electrical current producing apparatus – product – and – Having earth feature

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

429 44, 429 40, H01M 490

Patent

active

06117582&

ABSTRACT:
A high performance electrocatalyst is based on transition metal perovskites of praseodymium, samarium, terbium or neodymium which react with YSZ to form a product which is itself active as the cathode in a fuel cell. While PrCoO.sub.3 reacts with YSZ, the reaction product(s) do not result in severe degradation of cell performance. A fuel cell made with a cathode composed of only the reaction product of YSZ and PrCoO.sub.3 has good performance, indicating that this phase is itself not only a good conductor, but also a good catalyst for oxygen activation.

REFERENCES:
patent: 3377203 (1968-04-01), Mobius et al.
patent: 3460991 (1969-08-01), White, Jr.
patent: 3522097 (1970-07-01), Tedmon, Jr. et al.
patent: 3533849 (1970-10-01), Mitoff
patent: 3573993 (1971-04-01), Pabst et al.
patent: 4459341 (1984-07-01), Marchant et al.
patent: 4686158 (1987-08-01), Nishi et al.
patent: 4702971 (1987-10-01), Isenberg
patent: 4767518 (1988-08-01), Maskalick
patent: 4770955 (1988-09-01), Ruhl
patent: 4789561 (1988-12-01), Schaefer et al.
patent: 4847173 (1989-07-01), Mitsunaga et al.
patent: 4851303 (1989-07-01), Madou et al.
patent: 4885078 (1989-12-01), Spengler et al.
patent: 4894297 (1990-01-01), Singh et al.
patent: 4948680 (1990-08-01), Madou et al.
patent: 4997725 (1991-03-01), Pujare et al.
patent: 5001021 (1991-03-01), Maricle et al.
patent: 5021304 (1991-06-01), Ruka et al.
patent: 5037525 (1991-08-01), Badwal
patent: 5057362 (1991-10-01), Schroeder et al.
patent: 5064733 (1991-11-01), Krist et al.
patent: 5106706 (1992-04-01), Singh et al.
patent: 5114803 (1992-05-01), Ishihara et al.
patent: 5122425 (1992-06-01), Yoshida et al.
patent: 5143801 (1992-09-01), Bates
patent: 5298235 (1994-03-01), Worrell et al.
patent: 5298341 (1994-03-01), Khandkar et al.
patent: 5298343 (1994-03-01), Savadogo et al.
patent: 5308712 (1994-05-01), Seike et al.
patent: 5340664 (1994-08-01), Hartvigsen
patent: 5342704 (1994-08-01), Vasilow et al.
patent: 5366819 (1994-11-01), Hartvigsen et al.
patent: 5385792 (1995-01-01), Shiratori et al.
patent: 5403461 (1995-04-01), Tuller et al.
patent: 5409785 (1995-04-01), Nakano et al.
patent: 5432023 (1995-07-01), Yamada et al.
patent: 5432024 (1995-07-01), Soma et al.
patent: 5453330 (1995-09-01), Kawasaki et al.
patent: 5464654 (1995-11-01), Mizuno
patent: 5480738 (1996-01-01), Elangovan et al.
patent: 5527635 (1996-06-01), Tsukamoto et al.
patent: 5543239 (1996-08-01), Virkar et al.
patent: 5591537 (1997-01-01), Bagger et al.
patent: 5612149 (1997-03-01), Hartvigsen et al.
patent: 5620807 (1997-04-01), Mussell et al.
patent: 5629103 (1997-05-01), Wersing et al.
Tedmon, Jr., et al., "Cathode Materials and Performance in High-Temperature Zirconia Electrolyte Fuel Cells", J. Electrochem. Soc.: Electrochecmical Science, Sep. 1969, pp. 1170-1175.
Takeda, et al., "Cathodic Polarization Phenomena of Perovskite Oxide Electrodes with Stabilized Zirconia", J. Electrochem. Soc.: Electrochemical Science and Technology, Sep. 1987, pp. 2656-2661.
Ishihara et al., "Doped Perovskite Oxide, PrMnO.sub.3, as a New Cathode for Solid-Oxide Fuel Cells that Decreases the Operating Temperature", J. Am. Ceram. Soc., vol. 77, No. 6, Jun. 1994, pp. 1682-1684.
Yamamoto et al., "Perovskite-Type Oxides as Oxygen Electrodes for High Temperature Oxide Fuel Cells", Solid State Ionics 22, Elsevier Science Publishers B.V., North-Holland, Amsterdam, (1987), pp. 241-246. no month available.
Kamata et al., "Oxygen Reduction Behaviour at the Co-Fired La.sub.0.8 Sr.sub.0.2 MnO.sub.3 /YSZ Interface, as an SOFC Air Electrode", Proceedings of the 1st European Solid Oxide Fuel Cell Forum, Oct. 3-7, 1994, Lucerne-Switzerland, pp. 725-733.
Minh, "Ceramic Fuel Cells", J. Am. Ceram. Soc., 76[3], 1993, pp. 563-589. no month available.
Uchida et al., "New Preparation Method for Polymer-Electrolyte Fuel Cells", J. Electrochem. Soc., vol. 142, No. 2, Feb. 1995, pp. 463-468.
Tai et al. "Tape Casting and Sintering of Strontium-Doped Lanthanum Chromite for a Planar Solid Oxide Fuel Cell Bipolar Plate", J. Am. Ceram. Soc., 74[1], 1991, pp. 155-160. no month available.
Hayashi et al., "Sintering of Lanthanum Chromite Doped with Zinc or Copper", Journal of Materials Science Letters, 7, 1988, pp. 457-448. no month available.
Sakai et al., "Sinterability and Electrical Conductivity of Calcium-doped Lanthanum Chromites", Journal of Materials Science, 25, 1990, pp. 4531-4534. no month available.
Kawada et al., "Fabrication of a Planar Solid Oxide Fuel Cell by Tape-Casting and Co-Firing Method", Journal of the Ceramic Society of Japan, 100[6], 1992, pp. 847-850. no month available.
Meadowcraft et al., "Oxidation and Vaporization Processes in Lanthanum Chromite", Ceramic Bulletin, vol. 58, No. 6, 1979, pp. 610-615. no month available.
Yokokawa et al., "Thermodynamic Stabilities of Perovskite Oxides for Electrodes and Other Electrochemical Materials", Solid State Ionics, 52, 1992, pp. 43-56. no month available.
Steele, "Oxygen Ion Conductors and Their Technological Applications", Materials Science and Engineering, B13, 1992, pp. 79-87. no month available.
Chemical Abstract, 94:161192/20 (1994) no month available.
Chemical Abstract, 88:206576/30 (1988) no month available.
Chemical Abstract, 90: 129770/17 (1990) no month available.
Chemical Abstract, 94: 079443/10 (1994) no month available.
Chemical Abstract, 93: 325981 (1993) no month available.
Chemical Abstract, 93: 029003 (1993) no month available.
Chemical Abstract, 91: 081959 (1991) no month available.
Chemical Abstract, 94: 071641/09 (1994) no month available.
Chemical Abstract, 91: 059953 (1991) no month available.
Chemical Abstract, 93: 054896 (1993) no month available.
Derwent 89-141951/19--Abstract of JP 01-087,545 no month available.
Derwent 90-302452/40--Abstract of JP 02-215,005 no date available.
Derwent 90-302453/40--Abstract of JP 02-215,005 no date available.
Derwent 90-338562/45--Abstract of JP 02-243,768 no date available.
Derwent 90-338563/45--Abstract of JP 02-243,769 no date available.
Derwent 92-180619/22--Abstract of JP 04-118-866 no date available.
Berard, J. Solid State Chem., 1991, 90 (1), 126-46 (CA 114:92581p) no month available.
Hayami et al., Osaka Kogyo Gijutsu Shikenso Kiho 1977, 28(2), 98-106 (CA 87:174788z) no month available.
Jakobs, et al., Rev. Chim. Miner., 1980, 17(4), 283-98 (CA 94:54839q) no month available.
Ohno et al., Koen Yoshishu--Kotai Ionikusu Toronkai, 7th, 1979, 49-50 (CA 92:132003n) no month available.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Cathode composition for solid oxide fuel cell does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Cathode composition for solid oxide fuel cell, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Cathode composition for solid oxide fuel cell will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-94114

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.