Catalyzed oxime conversions

Details Catalyzed oxime conversions Catalyzed oxime conversions

1987-04-08

1989-11-28

Bond, Robert T.

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

564158, 564214, 564152, 564156, 540535, 540536, C07D10338, C07D20104, C07D103365

Patent

active

048839159

ABSTRACT:
A process for the catalyzed conversion fo oximes such as cyclohexanone oxime to amides such as caprolactam via a high conversion, high selectivity, long catalyst lifetime reaction over a HAMS-1B crystalline borosilicate-based catalyst composition.

REFERENCES:
patent: 3503958 (1920-03-01), Landis
patent: 4359421 (1982-11-01), Bell et al.
patent: 4697010 (1987-09-01), McMahon
Pauling "General Chemistry" 1st Ed., (Freeman)(1947) pp. 343-345.
Pawling "General Chemistry"3rd Ed., (Freeman)(1970) pp. 568-569.
Jerry March "Advanced Organic Chemistry": Reations Mechanisms and Structure (McGraw-Hill)(1968) pp. 226-227, 821-822.
Scott et al., Journal of Organic Chemistry, vol. 19, pp. 1815-1823 (1954).
Carey and Sundberg "Advanced Organic Chemistry" 2nd Edition, pp. 449-450 and 470 (Plenum)(1983).

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