Catalyzed Grignard coupling process

Details Catalyzed Grignard coupling process Catalyzed Grignard coupling process

1984-01-30

1985-03-26

Sutto, Anton H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Halogen containing

C07C 1726

Patent

active

045075131

ABSTRACT:
A 3-halo-2-methylphenylmagnesium halide is cross-coupled with a halobenzene using nickel(II) acetylacetonate as catalyst, producing a 3-halo-2-methyl[1,1'-biphenyl]. The amount of catalyst should be greater than 0.01 mole percent, but not more than 0.1 mole percent, based on the 3-halo-2-methylphenylmagnesium halide to achieve the best yields.

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