Catalyzed gas phase isomerization of nonconjugated 2-alkyl-3-mon

Details Catalyzed gas phase isomerization of nonconjugated 2-alkyl-3-mon Catalyzed gas phase isomerization of nonconjugated 2-alkyl-3-mon

1994-11-18

1995-08-08

Brust, Joseph Paul

Organic compounds -- part of the class 532-570 series

Organic compounds

Nitriles

C07C25330

Patent

active

054400678

ABSTRACT:
A gas phase process for the catalytic isomerization of 2-alkyl-3-monoalkenenitriles to 3- and/or 4-monoalkene nitriles, wherein a supported composition of zero-valent nickel and bidentate phosphite ligand is used as the catalyst.

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patent: 4298546 (1981-11-01), McGill
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Kurokawa, H. et al., "Skeletal Rearrangement of Unsaturated Nitriles over Solid-Base catalysts", Journal of Catalysis, 141, pp. 94-101 (1993).

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