Catalyzed conversion of tertiary butyl hydroperoxide to tertiary

Details Catalyzed conversion of tertiary butyl hydroperoxide to tertiary Catalyzed conversion of tertiary butyl hydroperoxide to tertiary

1987-09-08

1990-05-01

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

502167, 568910, 568914, 568922, 568571, C07C 3112, C07C 29132, C07C 2988, C07C 2704

Patent

active

049220349

ABSTRACT:
Tertiary butyl alcohol is prepared by the catalytic decomposition of tertiary butyl hydroperoxide, preferably in solution in tertiary butyl alcohol, in the presence of a metal porphine catalyst, optionally promoted with a C.sub.1 to C.sub.18 alkyl thiol and an amine, such as an iron (III) or manganese (III) porphine and, optionally, a thiol such as dodecane thiol and an amine, such as a heterocyclic amine (e.g., pyridine, quinoline, isoquinoline, imidazole or a 1-alkyl or 2-alkyl imidazole).

REFERENCES:
patent: 3360585 (1967-12-01), Winnick
patent: 3505360 (1970-04-01), Allison et al.
patent: 4508923 (1985-04-01), Taylor et al.
patent: 4547598 (1985-10-01), Sanderson et al.
patent: 4551553 (1985-11-01), Taylor et al.

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