Catalyzed alkali metal aluminum hydride production

Chemistry of inorganic compounds – Hydrogen or compound thereof

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C01B 624

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active

045633436

ABSTRACT:
A process for the production of alkali metal aluminum tetrahydrides from its elements by pressure hydrogenation, particularly characterized by production in the presence of an aluminate catalyst formed from NaAlCl.sub.4. The process is preferably carried out on a semi-continuous basis in which the active aluminum-containing heel is carried through to successive batches.

REFERENCES:
patent: 3138433 (1964-06-01), Guidice
patent: 3210150 (1965-10-01), Powers
patent: 3387933 (1968-06-01), Snyder
patent: 3387949 (1968-06-01), Snyder
patent: 3505036 (1970-04-01), Lindsay
Zakharkin et al., "Acad. of Sciences, USSR, Proceedings", vol. 145, Aug. 1962, pp. 656-658.
Ashby et al., "Inorg. Chem.," vol. 2, No. 3, Jun. 1963, pp. 499-504.

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