Catalytically active complex of titanium, cyclopentadienyl ligan

Details Catalytically active complex of titanium, cyclopentadienyl ligan Catalytically active complex of titanium, cyclopentadienyl ligan

1976-08-05

1977-09-06

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252431N, 260677H, 260690, C07F 728

Patent

active

040467902

ABSTRACT:
A catalytically active compound or complex from the complex "bis-titanocene" (U.S. Pat. No. 3,776,932 of Dec. 4, 1973 to G. P. Pez) by reaction thereof with ammonia at low temperature and in absence of contaminants, giving a characteristic powder x-ray diffraction pattern and characteristic radiation and e.s.r. spectra.

REFERENCES:
patent: 3776932 (1973-12-01), Pez
Dickens et al., Aus. J. Chem., 14, 555-561 (1961).
J.A.C.S. 94, 1219, 1226-1232, 1235, 1236 (1972).
Calderazzo, J. Organometal. Chem. 53, 179 to 182, 187 to 189, 191, 192, 195, 196 (1973).

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