Mineral oils: processes and products – By treatment of solid mineral – e.g. – coal liquefaction – etc. – Plural hydrogenation steps
Patent
1990-04-16
1991-09-03
Myers, Helane E.
Mineral oils: processes and products
By treatment of solid mineral, e.g., coal liquefaction, etc.
Plural hydrogenation steps
208417, 208418, 208409, C10G 100
Patent
active
050451804
ABSTRACT:
A process for catalytic multi-stage hydrogenation and liquefaction of coal to produce high yields of low-boiling hydrocarbon liquids containing low concentrations of nitogen compounds. First stage catalytic reaction conditions are 700.degree.-800.degree. F. temperature, 1500-3500 psig hydrogen partial pressure, with the space velocity maintained in a critical range of 10-40 lb coal/hr ft.sup.3 catalyst settled volume. The first stage catalyst has 0.3-1.2 cc/gm total pore volume with at least 25% of the pore volume in pores having diameters of 200-2000 Angstroms. Second stage reaction conditions are 760.degree.-870.degree. F. temperature with space velocity exceeding that in the first stage reactor, so as to achieve increased hydrogenation yield of low-boiling hydrocarbon liquid products having at least 75% removal of nitrogen compounds from the coal-derived liquid products.
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HRI Inc.
Myers Helane E.
Wilson Fred A.
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