Catalytic synthesis of urea from carbon monoxide and amine compo

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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528422, 560 24, 564 55, C07C12600

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active

048017442

ABSTRACT:
Process for the catalytic synthesis of nitrogen-containing organic compounds, comprising the reaction of carbon monoxide with at least one amino compound in a reaction mixture containing a catalyst based on selenium and a substituted pyridine. The process is particularly suitable for the synthesis of ureas and of their polymers.

REFERENCES:
Kiyoshi Kondo et al, "Selenium-Catalyzed Synthesis of Urea Derivatives from Amino Acid Esters, Carbon Monoxide, and Oxygen", 1979, Synthesis, pp. 735-736.
Noboru Sonoda et al, "A New Synthesis of Ureas. The Reaction of Ammonia or Aliphatic Amines with Carbon Monoxide in the Presence of Selenium", 1971, Journal of the American Chemical Society, p. 6344.
Chemistry Letters, pp. 373-374, 1972.

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