Catalytic suspension/dispersion preparation of polyamides from p

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528126, 528207, 528313, C08G 6930

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active

049259148

ABSTRACT:
This invention relates to a process for producing high molecular weight homopolyamides from a nylon salt formed from substantially equimolar proportions of a diamine and a dicarboxylic acid. The process comprises: (a) dispersing the nylon salt in its finely divided state having uniformly preblended therein a solid hypophosphite catalyst in a liquid aliphatic hydrocarbon, and polycondensing the dispersion either (b) at a temperature above 100.degree. C. but below the lower of the two temperatures representing the melting point of the nylon salt and the eventual polyamide product respectively where the polyamide product is a crystalline, or, (c) at a temperature up to 60.degree. C. above the glass transition temperature of the polyamide product where such product is amorphous.

REFERENCES:
patent: 3173898 (1965-03-01), Sum
patent: 3870685 (1975-03-01), Jones et al.

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