Catalytic removal of sulfur dioxide form flue gas

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component

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42324401, 42324409, 423247, 423437M, 423570, B01D 5350, B01D 5362

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active

058041532

ABSTRACT:
The present invention discloses a method for the catalytic reduction of sulfur dioxide, for example in flue gas, by carbon monoxide using lanthanum oxysulfide as the active catalyst. The catalyst is prepared from lanthanum oxide by hydration and sulfidization, the latter step being carried out in the gas stream itself. This method of preparation has more general applicability and can also be used as a method for the preparation of lanthanum, yttrium, gadolinium and lutetium oxysulfides generally.

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Ma et al. "Activation of La.sub.2 O.sub.3 For The Catalytic Reduction of SO.sub.2 By Co" J. of Catalysis, vol. 163 No. 2 pp. 271-278, Oct. 1996.
Baglio "lanthanum Oxysulfide As A Catayyst for The Oxidation of CO And COS By SO.sub.2 " Ind. Eng. Chem. Prod. Res. Dev. ; Mar. 1982; vol. 21 No. 1 pp. 38-41.
Hibert et al. "Flue Gas Desulphurisation : Catalytic Removal . . ." Applied Catalysis, 41 (1988, No Month) pp. 289-299.

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