Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1992-06-12
1993-10-19
Evans, Joseph E.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
5689098, C07C 2988, C07C 3112, C07C 2900
Patent
active
052547590
ABSTRACT:
Tertiary butyl alcohol contaminated with residual amounts of peroxide contaminants such as tertiary butyl hydroperoxide, ditertiary butyl peroxide, allyl tertiary butyl peroxide, etc., (which may be prepared, for example, by catalytically reacting propylene with tertiary butyl hydroperoxide to form propylene oxide and tertiary butyl alcohol) can be effectively catalytically treated under mild conversion conditions including a temperature of about 100.degree. to about 300.degree. C. with a catalyst comprising ferrous oxide to substantially completely decompose the peroxide contaminants to thereby provide a treated tertiary butyl alcohol product substantially free from contaminating quantities of such peroxides.
REFERENCES:
patent: 3624165 (1971-11-01), Dehn et al.
patent: 4219685 (1980-08-01), Savini
patent: 4704482 (1987-11-01), Sanderson et al.
patent: 4705903 (1987-11-01), Sanderson et al.
Knifton John F.
Sanderson John R.
Stockton Melvin E.
Bailey James L.
Evans Joseph E.
Priem Kenneth R.
Ries Carl G.
Texaco Chemical Company
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