Mineral oils: processes and products – Chemical conversion of hydrocarbons – Plural serial stages of chemical conversion
Patent
1983-04-06
1984-04-03
Davis, Curtis R.
Mineral oils: processes and products
Chemical conversion of hydrocarbons
Plural serial stages of chemical conversion
208 64, 208138, 208139, C10G 3506
Patent
active
044406282
ABSTRACT:
A process wherein, in a series of reforming zones, or reactors, each of which contains a bed, or beds of catalyst, the catalyst in the rearward most reforming zones is constituted of a high rhenium, platinum rhenium catalyst, viz., a catalyst comprising supported platinum and a relatively high concentration of rhenium relative to the platinum, and preferably the catalyst in the forwardmost reforming zone, or reactor of the series, is constituted of platinum, or platinum and a relatively low concentration of rhenium relative to the platinum. At least 30 percent, preferably from 40 percent to about 90 percent, of the rearward most reactors of the unit, or even 100 percent, based on the total weight of the catalyst in all of the reactors of the unit, contain a high rhenium, platinum rhenium catalyst, the weight ratio of rhenium:platinum being at least about 1.5:1. The beds of catalyst are contacted with a hydrocarbon or naphtha feed, and hydrogen, and the reaction continued for a period of at least 700 hours, preferably from about 700 hours to about 2750 hours, while conducting the reaction at temperatures ranging from about 850.degree. F. to about 950.degree. F. (E.I.T.), at pressures ranging from about 150 psig to about 350 psig, and at gas rates ranging from about 2500 SCF/B to about 4500 SCF/B.
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Markley Gerald E.
Winter William E.
Davis Curtis R.
Exxon Research and Engineering Co.
Proctor Llewellyn A.
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